Skip to main content
Log in

Regulation of the geometric parameters of mesoporous silica SBA-15 using the method of molecular layering and investigation of their porous structure

  • Published:
Nanotechnologies in Russia Aims and scope Submit manuscript

Abstract

The possibility of the directed regulation of geometric parameters of the porous structure of mesoporous oxide inorganic materials based on the controlled variation of the pore diameter has been studied. The pore sizes have been varied on the basis of synthesizing aluminum-oxygen nanolayers of the given thickness on the surface of silica SBA-15 pores using the molecular layering method. This made it possible to increase the thickness of the wall separating them without changing the distance between the pore centers. A formula for determining the pore radius of the obtained material has been proposed on the basis of data on the interplanar spacing and pore radius of the initial silica and the specific porosity of the modified silica.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. J. D. A. A. Soler-Illia, C. Sanchez, B. Lebeau, and J. Patarin, Chem. Rev. 102, 4093–4138 (2002).

    Article  Google Scholar 

  2. M. Kruk, M. Jaroniec, and A. Sayari, Microporous Mesoporous Mater. 27, 217–229 (1999).

    Article  CAS  Google Scholar 

  3. O. V. Belousov, V. A. Parfenov, M. A. Vershinina, and S. D. Kirik, “Study of Formation Processes of Mesostructured Silicas of MSM-41 Type Depending on Reaction Media Composition,” Vestn. Krasnoyarsk. Univ., Estestv. Nauki, No. 2, 100–106 (2003).

  4. D. Zhao, D. Feng, O. Huo, N. Melosh, G. H. Fredrickson, B. F. Chmelka, and G. D. Stucky, “Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores,” Science 279, 548–552 (1998).

    Article  CAS  Google Scholar 

  5. M. Zhao, T. L. Church, and A. T. Harris, “SBA-15 Supported Ni-Co Bimetallic Catalysts for Enhanced Hydrogen Production during Cellulose Decomposition,” Appl. Catal. B: Environ. 101, 522–530 (2011).

    Article  CAS  Google Scholar 

  6. M. Jaroniec, J. Choma, and M. Kruk, “Assessment of Reliability of the Horvath-Kawazoe Pore Size Analysis Method Using Argon Adsorption Isotherms on Ordered Mesoporous Silicas,” Colloids Surf. A: Physicochem. Eng. Asp. 214, 263–269 (2003).

    Article  CAS  Google Scholar 

  7. V. B. Aleskovskii, Chemistry of Solid Substances (Vyssh. Shkola, Moscow, 1978) [in Russian].

    Google Scholar 

  8. V. M. Smirnov, “Nanoscaled Structuring as a Way to Constructing New Solid Substances and Materials,” Russ. J. Gen. Chem. 72, 590–606 (2002).

    Article  CAS  Google Scholar 

  9. V. M. Smirnov, S. I. Kol’tsov, and V. B. Aleskovskii, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 17, 1759 (1974).

    CAS  Google Scholar 

  10. V. M. Smirnov et al., “Synthesis and Investigation of Aluminum Oxygen Layers on Surface of Silica,” J. Appl. Chem. USSR 49, 525–528 (1976).

    Google Scholar 

  11. V. M. Smirnov, S.I. Koltsov, and V. B. Aleskovskii, “Possible Control of Oxide Catalyst Activity, Depending on Chemical Composition of Atomic Surface Layer,” Zh. Fiz. Khim. 50, 1592–1594 (1976).

    CAS  Google Scholar 

  12. V. M. Smirnov, R. R. Rachkovskii, and G. P. Voronkov, “Synthesis and Study of Chemical Activity of Methoxyl Groups on Silicon Surface,” Zh. Obshch. Khim. 63, 278–282 (1993).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Yu. Arbenin.

Additional information

Original Russian Text © A.Yu. Arbenin, E.G. Zemtsova, V.M. Smirnov, 2012, published in Rossiiskie Nanotekhnologii, 2012, Vol. 7, Nos. 3–4.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arbenin, A.Y., Zemtsova, E.G. & Smirnov, V.M. Regulation of the geometric parameters of mesoporous silica SBA-15 using the method of molecular layering and investigation of their porous structure. Nanotechnol Russia 7, 117–121 (2012). https://doi.org/10.1134/S1995078012020036

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995078012020036

Keywords

Navigation