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Self-assembly of molecules of metal macrocyclic compounds in nanoreactors on the basis of biopolymer-immobilized matrix systems

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Abstract

The problems concerned with the processes of self-assembly of 3d-element aza-and thiazamacrocyclic complexes that happen in nanoreactors on the basis of metal hexacyanoferrate (II) gelatin-immobilized matrices under their contact with water solutions containing various (N, O, S)-donor atomic ligands and organic compounds having one or two carbonyl groups have been considered. It was noted that, in a series of cases, the variety of metal macrocyclic compounds obtained at self-assembly in such specific conditions considerably differs from that of metal macrocycles formed at the conditions traditional for chemical synthesis.

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  1. GOU VPO Kazan State Technological University, ul. K. Marksa 68, Kazan, 420015, Russia

    O. V. Mikhailov

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Original Russian Text © O.V. Mikhailov, 2010, published in Rossiiskie nanotekhnologii, 2010, Vol. 5, Nos. 1–2.

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Mikhailov, O.V. Self-assembly of molecules of metal macrocyclic compounds in nanoreactors on the basis of biopolymer-immobilized matrix systems. Nanotechnol Russia 5, 18–34 (2010). https://doi.org/10.1134/S1995078010010027

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