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Influence of a Directed Electric Field on the Features of Structural Formations in Nitrile-Butadiene Rubber Films

  • CHEMICAL PHYSICS OF POLYMER MATERIALS
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Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

The influence of the direction of a constant electric field on the properties and structural features of thin films of nitrile-butadiene rubber (NBR) formed on copper substrates from a solution in chloroform is studied. It is shown that the greatest effect in the modification of properties associated with structural transformations in the process of formation of elastomer films occurs on the negative electrode, the cathode, when the electric field lines are directed toward the electrode surface. The method of differential scanning calorimetry shows the structural differences between films formed outside and in the presence of electric fields. The films formed in the fields have different electrical characteristics from the films formed outside the field. The IR spectroscopy methods confirm the structuring and cyclization of NBR molecules on the surface of the film formed on the cathode.

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Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia

    L. S. Shibryaeva

  2. MIREA–Russian Technological University, Institute of Fine Chemical Technologies, Moscow, Russia

    L. S. Shibryaeva, N. N. Komova & V. A. Chizhenok

  3. Institute of Theoretical and Applied Electrodynamics, Russian Academy of Sciences, Moscow, Russia

    I. A. Boginskaya

Authors
  1. L. S. Shibryaeva
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  2. N. N. Komova
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  3. V. A. Chizhenok
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  4. I. A. Boginskaya
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Correspondence to N. N. Komova.

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Shibryaeva, L.S., Komova, N.N., Chizhenok, V.A. et al. Influence of a Directed Electric Field on the Features of Structural Formations in Nitrile-Butadiene Rubber Films. Russ. J. Phys. Chem. B 18, 275–282 (2024). https://doi.org/10.1134/S1990793124010184

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