Abstract
The enthalpies of combustion and enthalpies of formation of three trinitromethyl derivatives of 1,3,5-triazine are determined by the calorimetric method. The data obtained can be used for calculating the energy capabilities of related compounds by the method of replacing functional groups. As an example, the detonation characteristics of high-energy tris(trinitromethyl)-1,3,5-triazine are calculated.
REFERENCES
A. V. Shastin, T. I. Godovikova, and B. L. Korsunskiy, Russ. Chem. Rev. 72 (3), 279 (2003).
I. N. Zyuzin, I. Yu. Gudkova, and D. B. Lempert, Russ. J. Phys. Chem. B 14 (5), 804 (2020).
R. S. Stepanov, L. A. Kruglyakova, and A. M. Astakhov, Zh. Obshch. Khim. 77 (11), 1881 (2007).
A. V. Shastin, T. I. Godovikova, and B. L. Korsunskiy, Izv. Akad. Nauk. Ser. Khim., No. 6, 1194 (2011).
Ya. O. Inozemtsev, A. B. Vorobyev, A. V. Inozemtsev, and Yu. N. Matyushin, Goreniye Vzryv, No. 7, 260 (2014).
T. S. Kon’kova, Yu. N. Matyushin, E. A. Miroshnichenko, and A. B. Vorobyev, Izv. Akad. Nauk. Ser. Khim., No. 10, 1958 (2009).
M. J. Kamlet and S. J. Jacobs, J. Chem. Phys. 48 (3), 23 (1968).
M. N. Makhov and V. I. Arkhipov, Fiz. Goreniya Vzryva 25 (3), 87 (1989).
M. N. Makhov and V. I. Arkhipov, Russ. J. Phys. Chem. B 2, 602 (2008).
S. M. Skuratov, V. P. Kolesov, and A. F. Vorob’ev, Thermochemistry (Part II) (Moscow University, 1966).
E. A. Miroshnichenko, V. P. Lebedev, and Yu. N. Matyushin, Dokl. Akad. Nauk, 382 (4), 497 (2002).
M.-H. V. Huynh, M. A. Hiskey, E. L. Hartline, D. P. Montoya, and R. Gilardi, Angew. Chem. Int. Ed. 43, 4924 (2004).
A. V. Shastin, T. I. Godovikova, S. P. Golova, V. S. Kuz’min, L. I. Khmel’nitskii, and B. L. Korsunskii, Mendeleev Commun. 5 (1), 17 (1995).
A. V. Shastin and D. B. Lempert, Khim. Fiz. 35 (8), 44 (2016).
Funding
This study was carried out on the topic of a state assignment (registration nos. АААА-А21-121011990037-8, AAAA-A19-119022690098-3, АААА-А19-119071190040-5, and АААА-А18-118031490034-6).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors of this work declare that they have no conflicts of interest.
Additional information
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Kon’kova, T.S., Miroshnichenko, E.A., Shastin, A.V. et al. Thermochemical Properties of Trinitromethyl-1,3,5-Triazines. Russ. J. Phys. Chem. B 18, 166–171 (2024). https://doi.org/10.1134/S1990793124010111
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1990793124010111