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Phase Equilibria in the Nd3+–Water–Nitric Acid–TODGA–CO2 System and Efficiency of Supercritical Fluid Extraction of Neodymium Ions

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Abstract

This paper studied some equilibria in the Nd3+–water–nitric acid–TODGA (N,N,N,N-tetraoctyl diglycolamide)–CO2 system and the efficiency of extraction of Nd3+ ions from aqueous solutions into the supercritical (SC) CO2 phase at 313–353 K and 18.0–40.0 MPa. It was shown that, in the absence of TODGA, Nd3+ ions do not pass into the SC phase. The extraction efficiency increases with decreasing temperature and with increasing nitric acid concentration CNA in the aqueous solution. At 313 K, CNA > 1.5 mol/L, TODGA content not less than 100 mol/g-at. Nd, and CO2pressure ensuring complete dissolution of TODGA (19.0 MPa), Nd3+ completely pass into the SC phase. With increasing content of neodymium ions in the system, the pressure and amount of CO2 required for complete dissolution of TODGA increase. This is likely to be due to a decrease in the intensity of intermolecular interactions in the SC phase during the passage of polar Nd complexes with TODGA and nitrate ions into it.

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ACKNOWLEDGMENTS

Studies of samples by inductively coupled plasma atomic emission spectrometry were carried out using the equipment of the Center for Shared Use of Physical Methods for the Study of Substances and Materials, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia.

Funding

This work was supported of the Ministry of Science and Higher Education of the Russian Federation within the framework of the state assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    Ya. I. Zuev, M. O. Kostenko, O. O. Parenago & V. B. Baranovskaya

  2. Semenov Federal Research Center of Chemical Physics, Russian Academy of Science, 119991, Moscow, Russia

    M. Yu. Sinev

  3. Chemical Faculty, Lomonosov Moscow State University, 119991, Moscow, Russia

    O. O. Parenago

Authors
  1. Ya. I. Zuev
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  2. M. O. Kostenko
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  3. M. Yu. Sinev
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  4. O. O. Parenago
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  5. V. B. Baranovskaya
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Correspondence to Ya. I. Zuev.

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Zuev, Y.I., Kostenko, M.O., Sinev, M.Y. et al. Phase Equilibria in the Nd3+–Water–Nitric Acid–TODGA–CO2 System and Efficiency of Supercritical Fluid Extraction of Neodymium Ions. Russ. J. Phys. Chem. B 17, 1665–1674 (2023). https://doi.org/10.1134/S1990793123080110

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