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Equilibria in the Tetra-n-Octyldiglycolamide–Water–Nitric Acid–Carbon Dioxide System

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Abstract

Data on the solubility of tetra-n-octyldiglycolamide (TODGA) in supercritical (SC) carbon dioxide at 310–360 K and 80–250 bar were obtained. The effect of the presence of an aqueous phase containing nitric acid on the solubility of TODGA in SC-CO2 was studied. It is shown that the equilibria in the TODGA–water–nitric acid–CO2 system depend in a complex way on the content of each component in it and on the state parameters. The regularities characteristic of the TODGA–SC-CO2 binary system cannot be transferred to the TODGA–water–nitric acid–CO2 four-component system as the presence of highly polar water and nitric acid in it has a critically strong effect on the transition of TODGA into the fluid phase, despite the very low solubility of these compounds in it.

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Funding

This work was financially supported by the Rosatom State Corporation.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. O. Kostenko, O. O. Parenago & Ya. I. Zuev

  2. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    M. Yu. Sinev

  3. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. E. Lazhko

Authors
  1. M. O. Kostenko
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  2. O. O. Parenago
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  3. M. Yu. Sinev
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  4. Ya. I. Zuev
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  5. A. E. Lazhko
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Correspondence to M. O. Kostenko.

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Translated by L. Smolina

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Kostenko, M.O., Parenago, O.O., Sinev, M.Y. et al. Equilibria in the Tetra-n-Octyldiglycolamide–Water–Nitric Acid–Carbon Dioxide System. Russ. J. Phys. Chem. B 17, 1423–1433 (2023). https://doi.org/10.1134/S1990793123070072

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  • DOI: https://doi.org/10.1134/S1990793123070072

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