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Two-Stage Method for the Synthesis of Reactor Heterophase Thermoplastic Elastomers Based on Polypropylene

  • CHEMICAL PHYSICS OF POLYMER MATERIALS
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Abstract

A simple method for the two-stage synthesis in one reactor on one catalyst of heterophase thermoplastic elastomers based on isotactic polypropylene and an ethylene-propylene copolymer or an ethylene-propylene-1,4-hexadiene terpolymer is developed. The obtained materials, depending on the composition, have good elastomeric properties or behave like thermoplastics. Polymers in which ethylene units form long sequences have the best set of basic characteristics: high values of the elastic modulus, strength, and elongation at a break, as well as a low residual deformation.

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REFERENCES

  1. Thermoplastic Elastomers. Global Information, Inc. Premium Market Research Report. Published: May 1 (2021). https://www.giiresearch.com/report/go912435- thermoplastic-elastomers.html.

  2. Dong Hui, Zhong Jing, and A. I. Isayev, Polymers 13, 259 (2021).

    Article  Google Scholar 

  3. Weiyu Wang, Wei Lu, A. Goodwin, et al., Prog. Polym. Sci. 95, 1 (2019).

    Article  CAS  Google Scholar 

  4. T. M. Ushakova, E. E. Starchak, S. S. Gostev, et al., Russ. J. Phys. Chem. B 14 (3), 504 (2020).

    Article  CAS  Google Scholar 

  5. E. V. Prut, N. A. Erina, J. Karger-Kocsis, and T. I. Medintseva, J. Appl. Polym. Sci. 109, 1212 (2008).

    Article  CAS  Google Scholar 

  6. T. I. Medintseva, A. I. Sergeev, N. G. Schilkina, and E. V. Prut, Khim. Fiz. 42 (2023) (in press).

  7. P. Galli and G. Vecellio, J. Polym. Sci.: Part A: Polym. Chem. 42, 396 (2004).

    Article  CAS  Google Scholar 

  8. I. N. Meshkova, T. A. Ladygina, T. M. Ushakova, and L. A. Novokshonova, Polym. Sci., Part A, 44 (8), 824 (2002).

    Google Scholar 

  9. T. E. Nowlin, Y. V. Kissin, and K. P. Wagner, J. Polym. Sci. Part A: Polym. Chem. 26 (3), 755 (1988).

    Article  CAS  Google Scholar 

  10. D. M. Lisitsyn, T. I. Poznyak, and S. D. Rasumovskii, Kinet. Catal. 17 (4), 1049 (1976).

    CAS  Google Scholar 

  11. A. M. Aladyshev, A. N. Klyamkina, P. M. Nedorezova, and E. V. Kiseleva, Russ. J. Phys. Chem. B 14 (4), 691 (2020).

    Article  CAS  Google Scholar 

  12. R. S. Smykovskaya, O. P. Kuznetsova, T. I. Medintseva, et al., Russ. J. Phys. Chem. B 16, 346 (2022).

    Article  CAS  Google Scholar 

  13. I. N. Meshkova, T. M. Ushakova, N. M. Gul’tseva, et al., Polym. Sci., Ser. A 50 (11), 1161 (2008).

    Article  Google Scholar 

  14. T. M. Ushakova, N. M. Gul’tseva, I. N. Meshkova, and Yu. A. Gavrilov, Polimery 39 (10), 102 (1994).

    Article  Google Scholar 

  15. A. M. Aladyshev, O. P. Isichenko, P. M. Nedorezova, et al., Polym. Sci. USSR 33 (8), 1595 (1991).

    Article  Google Scholar 

  16. Yu. V. Kissin and L. A. Rishina, J. Polym. Sci.: Part A: Polym. Chem. 40, 1353 (2001).

    Article  Google Scholar 

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Funding

Work is done within the framework of the Fundamental Program scientific research Russian Academy of Sciences.

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Authors and Affiliations

  1. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    A. N. Klyamkina, P. M. Nedorezova & A. M. Aladyshev

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  1. A. N. Klyamkina
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  2. P. M. Nedorezova
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  3. A. M. Aladyshev
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Correspondence to P. M. Nedorezova.

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Klyamkina, A.N., Nedorezova, P.M. & Aladyshev, A.M. Two-Stage Method for the Synthesis of Reactor Heterophase Thermoplastic Elastomers Based on Polypropylene. Russ. J. Phys. Chem. B 17, 1355–1360 (2023). https://doi.org/10.1134/S1990793123060052

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  • DOI: https://doi.org/10.1134/S1990793123060052

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