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Preparation of Ni2P–N/TiO2 Catalyst in N2 Atmosphere and Its Benzofuran Hydrodeoxygenation Performance

  • KINETICS AND MECHANISM OF CHEMICAL REACTIONS, CATALYSIS
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Abstract

An alternative route to synthesize Ni2P–N/TiO2 in N2 atmosphere instead of H2 atmosphere by thermal treatment method was proposed, and the Ni2P–N/TiO2 catalyst was investigated in benzofuran hydrodeoxygenation (BF HDO) performance. X-ray diffraction (XRD), transmission electron microscope (TEM), N2-adsorption specific surface area measurements, CO uptake and X-ray photoelectron spectroscopy (XPS) were used to characterize the catalysts. The results showed that, the Ni2P–N/TiO2 catalyst possessed a smaller and highly dispersed Ni2P particles on the catalysts showed a higher benzofuran hydrodeoxygenation conversion (91.9%) and ethylcyclohexane selectivity (70.4%).

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ACKNOWLEDGMENTS

We are also grateful for the measurement assistants from Analysis and Testing Center of Northeast Petroleum University.

Funding

This work was supported by the Natural Science Foundation of Heilongjiang Province of China (QC2017005), the Youth Fund of Northeast Petroleum University (2018QNL-26), the Fund of Characteristic and Preponderant Discipline of Chemical Engineering andTechnology of Northeast Petroleum University (15041260273), the Fund of Scientific Research Foundation for the Introduction of Talent of Northeast Petroleum University (130502182).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing, Heilongjing, China

    Y. Wang, X. Dong, X. Dai & H. Song

  2. Innovation Institute for Sustainable Maritime Architecture Research and Technology, Qingdao University of Technology, Qingdao, Shandong, China

    B. Jiang

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  1. Y. Wang
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  2. X. Dong
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  4. X. Dai
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Correspondence to Y. Wang.

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Wang, Y., Dong, X., Jiang, B. et al. Preparation of Ni2P–N/TiO2 Catalyst in N2 Atmosphere and Its Benzofuran Hydrodeoxygenation Performance. Russ. J. Phys. Chem. B 17, 695–701 (2023). https://doi.org/10.1134/S1990793123030284

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