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Fraction of Free Volume in Defective Structures of Butadiene and Acrylonitrile Copolymers and Absorption of Low Molecular Compounds

  • CHEMICAL PHYSICS OF POLYMER MATERIALS
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Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

The correlation between the amount of sorbed solvents of different polarities, structures, and specific molar volumes (n-heptane, methyl acetate, and toluene) in crosslinked butadiene-nitrile elastomers in terms of equilibrium swelling and the value of free volume in their defective structures is established in this study by analogy with the dependence of the rotational mobility of nitroxyl radicals.

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RЕFERENCES

  1. N. M. Livanova, S. G. Karpova, L. A. Kovaleva, N. Ya. Ovsyannikov, A. A. Popov, Vysokomol. Soedin., Ser. A 58 (2), 121 (2016). https://doi.org/10.7868/S2308112016020127

    Article  Google Scholar 

  2. N. M. Livanova and A. A. Popov, Vysokomol. Soedin., Ser. A 58 (4), 345 (2016). https://doi.org/10.7868/S2308112016040088

    Article  Google Scholar 

  3. N. M. Livanova and A. A. Popov, Khim. Fiz. 36 (4), 67 (2017). https://doi.org/10.7868/S0207401X17040136

    Article  Google Scholar 

  4. N. M. Livanova and A. A. Popov, Khim. Fiz. 38 (3), 64 (2019). https://doi.org/10.1134/S0207401X19020109

    Article  Google Scholar 

  5. N. M. Livanova and A. A. Popov, Vysokomol. Soedin., Ser. A 59 (6), 542–547 (2017). https://doi.org/10.7868/S2308112017060074

    Article  Google Scholar 

  6. N. M. Livanova and A. A. Popov, Khim. Fiz. 39 (6), 81 (2020). https://doi.org/10.1134/S1990793120030215

    Article  Google Scholar 

  7. I. V. Kumpanenko, N. A. Ivanova, N. Yu. Kovaleva, N. A. Sakharova, K. A. Shiyanova, and A. V. Roshchin, Khim. Fiz. 40 (1), 45 (2021). https://doi.org/10.31857/S0207401X21010088

    Article  Google Scholar 

  8. G. M. Nazin, V. V. Dubikhin, I. L. Dalinger, A. I. Kazakov, and A. V. Nabatova, Khim. Fiz. 40 (1), 30 (2021). https://doi.org/10.31857/S0207401X21010118

    Article  Google Scholar 

  9. I. A. Var’yan, N. N. Kolesnikova, and A. A. Popov, Khim. Fiz. 40 (12), 1 (2021). https://doi.org/10.31857/S0207401X21120153

    Article  Google Scholar 

  10. Yu. V. Tertyshnaya, A. V. Khvatov, and A. A. Popov, Khim. Fiz. 41 (2), 86 (2022). https://doi.org/10.31857/S0207401X22020133

    Article  Google Scholar 

  11. Yu. P. Yampol’skii, Usp. Khim. 76 (1), 66 (2007). https://doi.org/10.1070/RC2007v076n01ABEH003629

    Article  CAS  Google Scholar 

  12. G. A. Sorokin, A. I. Kutsenko, R. A. Abramova, and E. G. Maksimenko, Vysokomol. Soedin., Ser. A 16 (2), 402 (1974).

    CAS  Google Scholar 

  13. G. A. Sorokin, E. A. Varfolomeeva, A. I. Kutsenko, and V. P. Merzlikina, Kauch. Rezina, No. 7, 17 (1979).

    Google Scholar 

  14. A. E. Chalykh and A. Avgonov, Vysokomol. Soedin., Ser. A 17 (6), 1291 (1975). http://polymsci.ru/index.php.

  15. S. A. Reitlinger, Permeability of Polymeric Materials (Khimiya, Moscow, 1974) [in Russian]. https://doi.org/10.1063/1.1700585

    Book  Google Scholar 

  16. B. S. Grishin, I. A. Tutorskii, and I. S. Yurovskaya, Vysokomol. Soedin., Ser. A 20 (9), 1967 (1978).

    CAS  Google Scholar 

  17. O. A. Chesnokova, Extended Abstract of Candidate’s Dissertation in Chemistry (Mosk. Inst. Tonk. Khim. Tekhnol., Moscow, 1985).

  18. Bukhina, M.F., Technical Physics of Elastomers (Khimiya, Moscow, 1984) [in Russian]. https://urss.ru/cgi-bin/db.pl?page=Search.

  19. I. H. Markovitz, J. Chem. Phys. 20 (5), 868 (1952). https://doi.org/10.1063/1.1700585

    Article  CAS  Google Scholar 

  20. A. R. Katritzky and D. E. Weiss, Chem. Brit, No. 2, 45 (1976).

    Google Scholar 

  21. P. Kuzay, W. Hoffman, W. Sauer, and W. Rimmer, Faserforschung und Textiltechnik. Zeitschrift fur Polymerforschung 26 (5), 219 (1975).

    CAS  Google Scholar 

  22. T. Fang, Macromolecules 23 (8), 2145 (1990).

    Article  CAS  Google Scholar 

  23. R. Simha and R. F. Boyer, J. Chem. Phys. 37, 1008 (1962). https://doi.org/10.1063/1.1733247

    Article  Google Scholar 

  24. G. M. Bartenev and F. G. Barteneva, Structure and Relaxation Properties of Polymers (Khimiya, Moscow, 1992) [in Russian]. https://www.studmed.ru/ search?g=DOI.

  25. A. A. Tager, Physical Chemistry of Polymers (Nauchnyi mir, Moscow, 2007) [in Russian]. http://elibrary.ru/ query_results.asp.

  26. J. Dechant, R. Danz, W. Kimmer, et al., Ultrarotspektroskopische Untersuchungen an Polymeren (Akademie-Verlag, Berlin, 1972). http://hdl.handle.net/ 2027.42/38788.

  27. N. V. Kozlova, F. F. Sukhov, and V. P. Bazov, Zavod. Lab. 31 (8), 968 (1965).

    CAS  Google Scholar 

  28. Yu. V. Kissin, V. I. Tsvetkova, and N. M. Chirkov, Vysokomol. Soedin., Ser. A 10 (2), 1092 (1968).

    CAS  Google Scholar 

  29. Yu. V. Kissin, I. T. Popov, D. M. Lisitsin, et al., Proizvod. Shin, Rezino-Tekhn. Asbesto-Tekhn. Izd., No. 7, 22 (1966).

  30. V. D. Yulovskaya and V. A. Shershnev, Reticulated Elastomers. Teaching Aid (Mosk. Inst. Tonk. Khim. Tekhnol. im. M.V. Lomonosova, Moscow, 1998) [in Russian].

  31. A. E. Nesterov, Handbook of the Physical Chemistry of Polymers, Vol. 1: Properties of Solutions and Mixtures of Polymers (Naukova dumka, Kiev, 1984) [in Russian]. https://litgu.ru/knigi/estesstv_nauki/377523-spravochnik-po-fizicheskoj-himii-polimerov-v-treh-tomah-tom-1-svojstva-rastvorov-i-smesej-polimerov.html.

  32. N. M. Livanova, S. G. Karpova, and A. A. Popov, Vysokomol. Soedin., Ser. A 51 (9), 1602 (2009). https://doi.org/10.1201/b18859

    Article  CAS  Google Scholar 

  33. N. M. Livanova, S. G. Karpova, and A. A. Popov, Vysokomol. Soedin., Ser. A 45 (3), 238 (2003). http://pascalfrancis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14673820.

  34. N. M. Livanova, S. G. Karpova, and A. A. Popov, Vysokomol. Soedin., Ser. A 53 (12), 2043 (2011).

    Google Scholar 

  35. V. V. Moiseev and T. I. Esina, Aging and Stabilization of Nitrile Rubbers (TsNIITENeftekhim, Moscow, 1978) [in Russian].

  36. E. Ya. Devirts, Butadiene-Nitrile Rubbers. Properties and Application (TsNIITENeftekhim, Moscow, 1972) [in Russian].

  37. E. B. Bokhyan, Yu. K. Ovchinnikov, G. S. Markova, and N. F. Bakeev, Vysokomol. Soedin., Ser. A 16 (2), 376 (1974). http://polymsci.ru/static/Archive/1978/ VMS_1978_T20_1/VMS_1978_T20_1_106-113.pdf.

  38. L. V. Sokolova and E. V. Matukhina, in Structure and Dynamics of Molecular Systems (Inst. Fiz. Mol. Krist. Ufim. Nauchn. Tsentra RAN, Ufa, 2008), Iss. XV, Vol. 1, p. 105 [in Russian].

  39. Vol’kenshtein, M.V., Configurational Statistics of Polymer Chains (Akad. Nauk SSSR, Moscow, 1959) [in Russian]. https://e-catalog.nlb.by/Record/BY-NLB-rr389.

  40. T. M. Birshtein and O. B. Ptitsyn, Conformations of Macromolecules, Ed. by M. V. Vol’kenshtein (Nauka, Moscow, 1964) [in Russian]. https://in.au1lib.org/ g/Биpштeйн%20T.M.

  41. J. E. Mark, J. Am. Chem. Soc. 89 (26), 6829 (1967). https://doi.org/10.1021/ja01001a067

    Article  CAS  Google Scholar 

  42. Korshak, V.V., Chain Nonuniformity in Polymers (Nauka, Moscow, 1977) [in Russian].

    Google Scholar 

  43. I. Prigogine, N. Trappeniers, and V. Mathot, Discus. Faraday Soc. 15, 93 (1953). https://doi.org/10.1039/DF9531500093

    Article  Google Scholar 

  44. D. Patterson, Macromolecules 2 (6), 672 (1969).

    Article  CAS  Google Scholar 

  45. J. D. Ferry, Viscoelastic Properties of Polymers (Wiley, New York, 1980). https://doi.org/10.4236/ojapps.2013.31B1017

    Book  Google Scholar 

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia

    N. M. Livanova, E. S. Pravada & A. A. Popov

  2. Moscow State University Institute of Fine Chemical Technologies, Moscow, Russia

    L. A. Kovaleva

  3. Plekhanov Russian University of Economics, Moscow, Russia

    A. A. Popov

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  1. N. M. Livanova
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  2. E. S. Pravada
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  3. L. A. Kovaleva
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  4. A. A. Popov
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Correspondence to N. M. Livanova.

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Livanova, N.M., Pravada, E.S., Kovaleva, L.A. et al. Fraction of Free Volume in Defective Structures of Butadiene and Acrylonitrile Copolymers and Absorption of Low Molecular Compounds. Russ. J. Phys. Chem. B 17, 738–744 (2023). https://doi.org/10.1134/S1990793123030077

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