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Cyanomethyl-Substituted Furazanoazepines: Synthesis, Structure, Enthalpy of Formation, and Ballistic Efficiency

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Abstract

7-Cyanomethyl-7Н-difurazano[3,4-b:3′,4′-f]furoxano[3″,4″-d]azepine (Az(O)CH2CN) and 7-cyanomethyl-7Н-trifurazano[3,4-b:3′,4′-d:3″,4″-f]azepine (AzCH2CN) are synthesized for the first time as potential dispersants of solid fuels for gas generator engines; their molecular structure, enthalpies of combustion, and formation are determined; and the relative aircraft flight range is estimated when using Az(O)CH2CN and AzCH2CN as fuel dispersants.

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Funding

This study was carried out on the topics of state assignment nos. AAAA-A19-119101690058-9, AAAA-A19-119120690042-9, and AAAA-A19-119092390076-7.

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Authors and Affiliations

  1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    D. B. Lempert, E. L. Ignatieva, A. I. Kazakov, A. V. Nabatova, G. V. Shilov, A. N. Utenyshev & S. M. Aldoshin

  2. Special Design and Technological Bureau “Technolog”, 192076, St. Petersburg, Russia

    A. I. Stepanov & D. V. Dashko

Authors
  1. D. B. Lempert
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  2. E. L. Ignatieva
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  3. A. I. Stepanov
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  4. D. V. Dashko
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  5. A. I. Kazakov
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  6. A. V. Nabatova
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  7. G. V. Shilov
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  8. A. N. Utenyshev
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  9. S. M. Aldoshin
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Corresponding author

Correspondence to D. B. Lempert.

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Lempert, D.B., Ignatieva, E.L., Stepanov, A.I. et al. Cyanomethyl-Substituted Furazanoazepines: Synthesis, Structure, Enthalpy of Formation, and Ballistic Efficiency. Russ. J. Phys. Chem. B 17, 702–709 (2023). https://doi.org/10.1134/S1990793123030065

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  • DOI: https://doi.org/10.1134/S1990793123030065

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