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Introduction of Spin Probes into Graphite Oxide Membranes with the Use of Supercritical Carbon Dioxide

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Abstract

A nitroxyl spin probe is introduced into graphite oxide membranes from a solution in supercritical carbon dioxide in various modes. It is shown that a slow pressure release makes it possible to introduce the probe without destroying the orientational order of graphene layers, i.e., without destroying the internal structure of a membrane.

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ACKNOWLEDGMENTS

The authors thank Professor A.V. Talyzin (Umea University, Sweden) for providing the graphite oxide membrane and Professor N.Yu. Ignatieva (Department of Chemistry, Moscow State University, Russia) for help in recording the IR spectra.

Funding

This study was performed as part of a project of the Russian Scientific Foundation (grant no. 21-73-00124) and supported in part by Moscow State University’s Program of Development.

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Authors and Affiliations

  1. Semenov Federal Research Center of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    N. A. Chumakova, A. V. Kaplin & A. T. Rebrikova

  2. Moscow State University, 119991, Moscow, Russia

    N. A. Chumakova, A. E. Lazhko, M. V. Matveev & A. V. Kaplin

Authors
  1. N. A. Chumakova
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  2. A. E. Lazhko
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  3. M. V. Matveev
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  4. A. V. Kaplin
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  5. A. T. Rebrikova
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Corresponding author

Correspondence to N. A. Chumakova.

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Translated by E. Glushachenkova

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Chumakova, N.A., Lazhko, A.E., Matveev, M.V. et al. Introduction of Spin Probes into Graphite Oxide Membranes with the Use of Supercritical Carbon Dioxide. Russ. J. Phys. Chem. B 16, 1397–1401 (2022). https://doi.org/10.1134/S1990793122080073

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  • DOI: https://doi.org/10.1134/S1990793122080073

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