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Phase Equilibrium in the Binary Water–Propane/Butane System

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Abstract

Phase equilibrium in the water–propane/butane system is studied with the use of a high-pressure optical cell within a range of temperatures of 403 to 443 K and pressures of 5.28—20.66 MPa, and type V phase behavior is established. The water solubility in a supercritical propane–butane mixture is estimated under the mentioned conditions from the characteristics of the vapor branch of phase equilibrium in the water–propane/butane mixture and described by the Peng–Robinson equation of state in combination with the Mukhopadhyay–Rao mixing rule.

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ACKNOWLEDGMENTS

This study was performed on the equipment of the Shared Facilities Center “Nanomaterials and Nanotechnologies,” Kazan National Research Technological University.

Funding

This study was financially supported by the Russian Science Foundation (project no. 19-73-10029).

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Authors and Affiliations

  1. Kazan National Research Technological University, 420015, Kazan, Russia

    T. R. Bilalov, V. F. Khairutdinov, I. Sh. Khabriev & F. M. Gumerov

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  1. T. R. Bilalov
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  2. V. F. Khairutdinov
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  3. I. Sh. Khabriev
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  4. F. M. Gumerov
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Corresponding author

Correspondence to T. R. Bilalov.

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Translated by E. Glushachenkova

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Bilalov, T.R., Khairutdinov, V.F., Khabriev, I.S. et al. Phase Equilibrium in the Binary Water–Propane/Butane System. Russ. J. Phys. Chem. B 16, 1341–1346 (2022). https://doi.org/10.1134/S199079312208005X

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  • DOI: https://doi.org/10.1134/S199079312208005X

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