Abstract
Single-phase Ce–Zr oxides with a fluorite structure were synthesized by the solvothermal method in an isopropanol medium. Synthesis was performed at the supercritical parameters of isopropanol. The effect of the synthesis parameters on the characteristics of the obtained materials (specific surface area, morphology, particle size, phase composition) was established. Ni (5 wt %) and Ni + Co (5 wt %) were deposited at a ratio of 1 : 1 by incipient wetness impregnation. The structure and properties of samples were characterized by physicochemical methods, such as X-ray diffraction, Raman spectroscopy, high-resolution transmission electron microscopy, and temperature-programmed reduction by hydrogen. The dependences of the conversion of reagents (CH4 and CO2), the yield of hydrogen, and the Ce/Zr ratio in the Dry reforming of methane (DRM) reaction on the composition of catalysts were studied. The effect of the composition of a deposited metallic component and the Ce/Zr ratio in the support on the catalytic properties and catalysts stability in the DRM reaction was shown.
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REFERENCES
W.-J. Jang, J.-O. Shim, H.-M. Kim, S.-Y. Yoo, and H.-S. Roh, Catal. Today 324, 15 (2019).
M. Aresta and A. Dibenedetto, Dalton Trans., 2975 (2007).
E. le Sache and T. R. Reina, Prog. Energy Combust. Sci. 89, 10970 (2022).
D. Pakhare and J. Spivey, Chem. Soc. Rev. 43, 7813 (2014).
I. V. Yentekakis and G. A. Panagiotopoulou, Appl. Catal. B: Environ. 296, 120210 (2021).
A. Kambolis, H. Matralis, A. Trovarelli, and Ch. Papadopoulou, Appl. Catal. A: Gen. 377, 16 (2010).
Y. Lyu, J. Jocz, R. Xu, E. Stavitski, and C. Sievers, ACS Catal. 10, 11235 (2020).
M. A. Salaev, L. F. Liotta, and O. V. Vodyankina, Int. J. Hydrogen Energy 47, 4489 (2022).
M. A. Vasiliades, P. Djinovi, L. F. Davlyatova, A. Pintar, and A. M. Efstathiou, Catal. Today 299, 201 (2018).
Y. Khani, F. Bahadoran, Z. Shariatinia, M. Varmazyari, and N. Safari, Ceram. Int. 46, 25122 (2020).
I. Luisetto, S. Tuti, C. Romano, M. Boaro, E. Di, J. Kopula, S. Senthil, and K. Selvakumar, J. CO2 Util. 30, 63 (2019).
J. A. Montoya, E. Romero-Pascual, C. Gimon, P. del Angel, and A. Monzin, Catal. Today 63, 71 (2000).
L. Wu, X. Xie, H. Ren, and X. Gao, Mater. Today: Proc. 42, 153 (2021).
S. Das, A. Jangam, S. Jayaprakash, S. Xi, K. Hidajat, K. Tomishige, and S. Kawi, Appl. Catal. B: Environ. 290, 119998 (2021).
C. Pizzolitto, E. Pupulin, F. Menegazzo, E. Ghedini, A. di Michele, M. Mattarelli, G. Cruciani, and M. Signoretto, Int. J. Hydogen Energy 44, 28065 (2019).
S. Bernal, J. J. Calvino, M. A. Cauqui, J. M. Gatica, C. Lopez Cartes, J. A. Perez Omil, and J. M. Pintado, Catal. Today 77, 385 (2003).
C. M. Damaskinos, J. Zavasnik, P. Djinovic, and A. M. Efstathiou, Appl. Catal. B: Environ. 296, 120321 (2021).
L. P. Teh, H. D. Setiabudi, S. N. Timmiati, M. A. A. Aziz, N. H. R. Annuar, and N. N. Ruslan, Chem. Eng. Sci. 242, 116606 (2021).
J. Sasson Bitters, T. He, E. Nestler, S. D. Senanayake, J. G. Chen, and C. Zhang, J. Energy Chem. 68, 124 (2022).
F. Sharifianjazi, A. Esmaeilkhanian, L. Bazli, S. Eskandarinezhad, S. Khaksar, P. Shafiee, M. Yusuf, B. Abdullah, P. Salahshour, and F. Sadeghi, Int. J. Hydrogen Energy (2021, in press).
Z. Wu, B. Yang, S. Miao, W. Liu, J. Xie, S. Lee, M. J. Pellin, D. Xiao, D. Su, and D. Ma, ACS Catal. 9, 2693 (2019).
S. Sengupta, K. Ray, and G. Deo, Int. J. Hydrogen Energy 39, 11462 (2014).
X. Li, J. Ai, W. Li, and D. Li, Front. Chem. Eng. China 4, 476 (2010).
W. Tu, M. Ghoussoub, C. V. Singh, and Y. H. C. Chin, J. Am. Chem. Soc. 139, 6928 (2017).
D. P. F. Souza, C. L. de Silva, and V. R. Mastelaro, J. Eur. Ceram. Soc. 23, 273 (2003).
T. G. Kuznetsova and V. A. Sadykov, Kinet. Catal. 49, 840 (2008).
A. le Gal, S. Abanades, and G. Flamant, Energy Fuels 25, 4836 (2011).
A. N. Kharlanov, A. O. Turakulova, A. V. Levanov, and V. V. Lunin, Russ. J. Phys. Chem. A 92, 678 (2018).
F. Zamar, A. Trovarelli, C. de Leitenburg, and G. Dolcetti, Studies Surf. Sci. Catal. B 101, 1283 (1996).
E. A. Trusova, A. A. Khrushcheva, and K. V. Vokhmintcev, J. Eur. Ceram. Soc. 32, 1977 (2012).
A. Horváth, G. Stefler, O. Geszti, A. Kienneman, A. Pietraszek, and L. Guczi, Catal. Today 169, 102 (2011).
I. Luisetto, S. Tuti, and E. di Bartolomeo, Int. J. Hydrogen Energy 37, 15992 (2012).
M. Hirano and E. Kato, J. Ceram. Soc. Jpn. 104, 958 (1996).
A. A. Galkin and V. V. Lunin, Russ. Chem. Rev. 74, 21 (2005).
C. Slostowski, S. Marre, O. Babot, T. Toupance, and C. Aymonier, Langmuir 28, 16656 (2012).
Y. Hakuta, H. Hayashi, and K. Arai, Curr. Opin. Solid State Mater. Sci. 7, 341 (2003).
A. Cabanas, J. A. Darr, E. Lester, and M. Poliakoff, Chem. Commun., 901 (2000).
J. A. Darr and M. Poliakoff, Chem. Rev. 99, 495 (1999).
E. K. C. Pradeep, T. Habu, H. Tooriyama, M. Ohtani, and K. Kobiro, J. Supercrit. Fluids 97, 217 (2015).
P. Wang, K. Ueno, H. Takigawa, and K. Kobiro, J. Supercrit. Fluids 78, 124 (2013).
S. P. Gubin and E. Yu. Buslaeva, Russ. J. Phys. Chem. B 3, 1172 (2009).
M. Y. Smirnova, S. N. Pavlova, T. A. Krieger, Y. N. Bespalko, V. I. Anikeev, Y. A. Chesalov, V. V. Kaichev, M. V. Mesetseva, and V. A. Sadykov, Russ. J. Phys. Chem. B 11, 1312 (2017).
Y. Bespalko, E. Smal, M. Simonov, K. Valeev, and V. Fedorova, Energies 13, 3365 (2020).
M. Simonov, Y. Bespalko, E. Smal, K. Valeev, V. Fedorova, T. Krieger, and V. Sadykov, Nanomaterials 10, 1 (2020).
A. Auxéméry, B. B. Frias, E. Smal, K. Dziadek, G. Philippot, P. Legutko, M. Simonov, S. Thomas, A. Adamski, V. Sadykov, K. Parkhomenko, A.-C. Rogerb, and C. Aymonier, J. Supercrit. Fluids 162, 104855 (2020).
V. Fedorova, M. Simonov, K. Valeev, Y. Bespalko, E. Smal, N. Eremeev, E. Sadovskaya, T. Krieger, and A. Ishchenko, Energies 14, 2973 (2021).
V. Sánchez Escribano, E. Fernández, M. Panizza, C. Resini, J. M. Gallardo Amores, and G. Busca, Solid State Sci. 5, 1369 (2003).
A. Romero-Núñez and G. Diaz, RSC Adv. 5, 54571 (2015).
M. Y. Smirnova, A. S. Bobin, S. N. Pavlova, A. V. Ishchenko, A. V. Selivanova, V. V. Kaichev, S. V. Cherepanova, T. A. Krieger, M. V. Arapova, A.-C. Rogerb, A. Adamski, and V. A. Sadykov, Open Chem. 15, 412 (2017).
R. D. Shannon, Acta Crystallogr., Sect. A 32, 751 (1976).
M. Arapova, E. Smal, Y. Bespalko, V. Fedorova, K. Valeev, S. Cherepanova, A. Ischenko, V. Sadykov, and M. Simonov, Int. J. Hydrogen Energy 46, 39236 (2021).
H. Roh, K. Young, and W. Lai, Catal. Today 146, 71 (2009).
ACKNOWLEDGMENTS
The authors thank the Shared Facilities Center “High Technologies and Analytics of Nanosystems” of Novosibirsk State University for conducting the measurements on their scientific equipment.
Funding
This study was performed as part of project no. 18-73-10167 of the Russian Science Foundation.
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Translated by E. Glushachenkova
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Bespalko, Y.N., Fedorova, V.E., Smal, E.A. et al. Ni and Ni–Co Catalysts Based on Mixed Ce–Zr Oxides Synthesized in Isopropanol Medium for Dry Reforming of Methane. Russ. J. Phys. Chem. B 16, 1384–1396 (2022). https://doi.org/10.1134/S1990793122080048
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DOI: https://doi.org/10.1134/S1990793122080048