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Selectivity of Ethylaluminium Dichloride–Proton Donor Complex Catalysts from the C4 Fraction in Initiating the Oligomerization of Isobutylene

  • KINETICS AND MECHANISM OF CHEMICAL REACTIONS, CATALYSIS
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Abstract

The mechanism of isobutylene initiation in the presence of ethylaluminum dichloride–proton donor (water, phenol, hydrochloric acid) complex catalysts is studied by the ab initio HF/3-21G method. The energetics of these reactions are estimated, and the values of their activation energy and thermal effects are obtained. It is established that among the studied catalysts, an increase in the activation energy of the initiation of isobutylene oligomerization is symbatic with the selectivity of this process from the C4 fraction.

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REFERENCES

  1. V. A. Babkin, G. E. Zaikov, and K. S. Minsker, Quantum-Chemical Aspect of Cationic Polymerization of Olefins (Gilem, Ufa, 1996) [in Russian].

    Google Scholar 

  2. V. D. Petrova, N. N. Rzhevskaya, N. V. Shcherbakova, Yu. A. Sangalov, and K. S. Minsker, Dokl. Akad. Nauk SSSR 233, 602 (1977).

    CAS  Google Scholar 

  3. V. D. Petrova, N. N. Rzhevskaya, N. V. Shcherbakova, Yu. A. Sangalov, and K. S. Minsker, Russ. Chem. Bull. 27, 1194 (1978).

    Article  Google Scholar 

  4. G. A. Razuvaev, Yu. A. Sangalov, Yu. B. Yasman, and K. S. Minsker, Dokl. Akad. Nauk SSSR, Ser. Khim. 239, 338 (1978).

    CAS  Google Scholar 

  5. N. I. Kol’tsov, Russ. J. Phys. Chem. B 14, 765 (2020).

    Article  Google Scholar 

  6. A. M. Tereza, G. L. Agafonov, E. K. Anderzhanov, S. P. Medvedev, S. V. Khomik, S. K. Petrov, and M. V. Chernyshov, Russ. J. Phys. Chem. B 14, 654 (2020). https://doi.org/10.1134/S1990793120040247

    Article  CAS  Google Scholar 

  7. D. N. Tarasov and R. P. Tiger, Russ. J. Phys. Chem. B 13, 478 (2019). https://doi.org/10.1134/S1990793119030138

    Article  CAS  Google Scholar 

  8. V. M. Volokhov, T. S. Zyubina, A. V. Volokhov, E. S. Amosova, D. A. Varlamov, D. B. Lempert, and L. S. Yanovskii, Russ. J. Phys. Chem. B 15, 12 (2021). https://doi.org/10.1134/S1990793121010127

    Article  CAS  Google Scholar 

  9. V. G. Tsirel’son, Quantum Chemistry. Molecules, Molecular Systems and Solids (Binom, Moscow, 2010) [in Russian].

    Google Scholar 

  10. V. A. Babkin, D. S. Andreev, A. V. Ignatov, et al., Oxid. Commun. 42, 56 (2019).

    CAS  Google Scholar 

  11. V. A. Babkin, A. V. Kozhuhova, Yu. A. Vashuta, et al., Oxid. Commun. 42, 275 (2019).

    CAS  Google Scholar 

  12. V. A. Babkin, D. S. Andreev, A. V. Ignatov, et al., Oxid. Commun. 43, 24 (2020).

    CAS  Google Scholar 

  13. V. A. Babkin, D. S. Andreev, and A. V. Ignatov, Oxid. Commun. 43, 171 (2020).

    CAS  Google Scholar 

  14. A. A. Granovsky, Firefly, Version 8, 2013. http://classic.chem.msu.su/gran/firefly/index.html.

  15. M. W. Schmidt, K. K. Baldridge, and J. A. Boatz, J. Comput. Chem. 14, 1347 (1993).

    Article  CAS  Google Scholar 

  16. B. M. Bode and M. S. Gordon, J. Mol. Graph., No. 16, 133 (1998).

  17. G. A. Olah, Friedel-Crafts Chemistry (Wiley, New York, 1973).

    Google Scholar 

  18. S. Pasynkiewicz, M. Boleslawski, and A. Sadownik, J. Organomet. Chem. 113, 303 (1976).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia

    G. E. Zaikov & M. I. Artsis

  2. Volgograd State Technical University, Sebryakovsky Branch, Mikhailovka, Volgograd Region, Russia

    D. S. Andreev & A. V. Ignatov

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  1. G. E. Zaikov
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  2. M. I. Artsis
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  3. D. S. Andreev
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  4. A. V. Ignatov
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Correspondence to G. E. Zaikov.

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Zaikov, G.E., Artsis, M.I., Andreev, D.S. et al. Selectivity of Ethylaluminium Dichloride–Proton Donor Complex Catalysts from the C4 Fraction in Initiating the Oligomerization of Isobutylene. Russ. J. Phys. Chem. B 16, 606–614 (2022). https://doi.org/10.1134/S1990793122040169

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  • DOI: https://doi.org/10.1134/S1990793122040169

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