Abstract
The influence of the electric field on the interaction of CO with oxidized copper-nickel nanoparticles is studied. It is established that the restoration of the surface of nanoparticles is possible at potentials of φ ≤ +5 V applied to the sample relative to the ground potential, and at φ ≥ +5 V it is difficult. The most probable mechanism of the influence of the electric field on the reduction rate of the surface oxide is related to the spatial orientation of CO molecules.
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REFERENCES
S. Shaik, D. Danovich, J. Joy, et al., J. Am. Chem. Soc. 142, 12551 (2020).
R. Meir, H. Chen, W. Lai, et al., ChemPhysChem 11, 301 (2010).
S. Ciampi, N. Darwish, H. M. Aitken, et al., Chem. Soc. Rev. 47, 5146 (2018).
S. Shaik, R. Ramanan, D. Danovich, et al., Chem. Soc. Rev. 47, 5125 (2018).
T. Stuyver, D. Danovich, J. Joy, et al., Wiley Interdisc. Rev.: Comput. Mol. Sci. 10, e1438 (2020).
A. C. Aragonès, N. L. Haworth, N. Darwish, et al., Nature (London, U.K.) 531, 88 (2016).
L. Martín, E. Molins, and A. Vallribera, New J. Chem. 40, 10208 (2016).
S. Shaik, S. P. de Visser, and D. Kumar, J. Am. Chem. Soc. 126, 11746 (2004).
L. Rincón, J. R. Mora, F. J. Torres, et al., Chem. Phys. 477, 1 (2016).
M. McEntee, A. Stevanovic, W. Tang, et al., J. Am. Chem. Soc. 137, 1972 (2015).
C. Peineke, P. Davoodi, M. Seipenbusch, et al., J. Nanosci. Nanotechnol. 11, 8628 (2011).
H. Hakkinen, W. Abbet, A. Sanchez, et al., Angew. Chem. Int. Ed. 42, 1297 (2003).
B. Yoon, H. Häkkinen, U. Landman, et al., Science (Washington, DC, U. S.) 307, 403 (2005).
G. Pacchioni, L. Giordano, and M. Baistrocchi, Phys. Rev. Lett. 94, 226104 (2005).
T. N. Rostovshchikova, V. V. Smirnov, V. M. Kozhevin, et al., Ross. Nanotekhnol. 2 (1–2), 47 (2007).
E. M. Balashov, A. K. Gatin, M. V. Grishin, F. I. Dalidchik, N. N. Kolchenko, and B. R. Shub, Russ. J. Phys. Chem. B 4, 340 (2010).
S. Y. Sarvadii, A. K. Gatin, V. A. Kharitonov, et al., Nanomaterials 11, 279 (2021).
S. Y. Sarvadiy, A. K. Gatin, M. V. Grishin, et al., Gold Bull. 52, 61 (2019).
M. V. Grishin, A. K. Gatin, V. G. Slutskii, A. S. Fedotov, V. A. Kharitonov, and B. R. Shub, Russ. J. Phys. Chem. B 14, 266 (2020).
M. V. Grishin, A. K. Gatin, V. G. Slutskii, A. S. Fedotov, V. A. Kharitonov, and B. R. Shub, Russ. J. Phys. Chem. B 14, 547 (2020).
M. V. Grishin, A. K. Gatin, V. G. Slutsky, A. S. Fedotov, V. A. Kharitonov, and B. R. Shub, Russ. J. Phys. Chem. B 15, 373 (2021).
M. V. Grishin, A. K. Gatin, V. G. Slutskii, A. S. Fedotov, V. A. Kharitonov, and B. R. Shub, Russ. J. Phys. Chem. B 15, 777 (2021).
F. Zhao, M. Gong, Y. Zhang, et al., J. Porous Mater. 23, 733 (2016).
I. Zegkinoglou, L. Pielsticker, Z.-K. Han, et al., J. Phys. Chem. C 123, 8421 (2019).
Scanning Tunnelling Microscopy I. General Principles and Applications to Clean and Absorbate-Covered Surfaces, Ed. by H.-J. Guntherodt and R. Wiesendanger (Springer, Berlin, 1992).
G. Binnig, H. Rohrer, C. Berber, et al., Appl. Phys. Lett. 40, 178 (1981).
E. Meyer, H. J. Hug, and R. Bennewitz, Scanning Probe Microscopy (Springer, Berlin, 2004).
R. J. Hamers and Y. J. Wang, Chem. Rev. 96, 1261 (1996).
R. J. Hamers, R. M. Tromp, and J. E. Demuth, Phys. Rev. Lett. 56, 1972 (1986).
M. V. Grishin, A. K. Gatin, S. Yu. Sarvadii, and B. R. Shub, Nanotechnol. Russ. 12, 589 (2017).
R. O. Apaydin, B. Ebin, and S. Gurmen, AIP Conf. Proc. 1569, 57 (2013).
J. E. Huheey, Inorganic Chemistry: Principles of Structure and Reactivity (Harper and Row, New York, 1983).
Handbook of Physical Quantities, Ed. by I. S. Grigor’ev and E. Z. Meilikhov (Energoatomizat, Moscow, 1991; CRC, Boca Raton, NY, 1996).
X. C. Huang, H. Lu, H. B. He, et al., Philos. Mag. 95, 3896 (2015).
A. Kitla, O. V. Safonova, and K. Fottinger, Catal. Lett. 143, 517 (2013).
Funding
This study was carried out as part of a state task of the Semenov Federal Research Center of Chemical Physics, Russian Academy of Sciences and with the financial support of the Russian Foundation for Basic Research, grant no. 20-03-00419.
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Gatin, A.K., Grishin, M.V., Prostnev, A.S. et al. Interaction of Carbon Monoxide with a Nano-Structured Copper-Nickel Coating on Graphite in the Presence of an Electric Field. Russ. J. Phys. Chem. B 16, 468–473 (2022). https://doi.org/10.1134/S1990793122030046
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DOI: https://doi.org/10.1134/S1990793122030046