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Interaction of Carbon Monoxide with a Nano-Structured Copper-Nickel Coating on Graphite in the Presence of an Electric Field

  • CHEMICAL PHYSICS OF NANO-MATERIALS
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Abstract

The influence of the electric field on the interaction of CO with oxidized copper-nickel nanoparticles is studied. It is established that the restoration of the surface of nanoparticles is possible at potentials of φ ≤ +5 V applied to the sample relative to the ground potential, and at φ ≥ +5 V it is difficult. The most probable mechanism of the influence of the electric field on the reduction rate of the surface oxide is related to the spatial orientation of CO molecules.

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Funding

This study was carried out as part of a state task of the Semenov Federal Research Center of Chemical Physics, Russian Academy of Sciences and with the financial support of the Russian Foundation for Basic Research, grant no. 20-03-00419.

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Correspondence to M. V. Grishin.

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Gatin, A.K., Grishin, M.V., Prostnev, A.S. et al. Interaction of Carbon Monoxide with a Nano-Structured Copper-Nickel Coating on Graphite in the Presence of an Electric Field. Russ. J. Phys. Chem. B 16, 468–473 (2022). https://doi.org/10.1134/S1990793122030046

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  • DOI: https://doi.org/10.1134/S1990793122030046

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