Skip to main content
SpringerLink
Log in

Kinetics of the Decomposition of 1,1-Diamino-2,2-Dinitroethylene (FOX-7). Part 4: Comparison of the Decomposition Reactions of FOX-7 and Its Diazacyclic Derivatives

  • COMBUSTION, EXPLOSION, AND SHOCK WAVES
  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

The kinetics of the thermal decomposition of diazacyclic derivatives of 1,1-diamino-2,2-dinitroethylene (FOX-7) in a dilute solution of nitrobenzene and in the solid phase are studied by manometric and calorimetric methods. The activation energy data obtained for the solution are used for comparison with quantum chemical calculations and for establishing the relationship between the stability of compounds and the structure of the molecules. The decomposition of these derivatives in solution proceeds according to the same mechanism as the decomposition of FOX-7. Their activation energies decrease with the increasing C=C bond length and are in close agreement with the published data on quantum chemical calculations. By the nature of decomposition in the solid state, these compounds differ significantly from FOX-7. This difference is due to the fact that the condensed products of their decomposition are not solid but liquid compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.

Similar content being viewed by others

REFERENCES

  1. A. J. Bellamy, Struct. Bonding 125, 1 (2007). https://doi.org/10.1007/430_2006_054

    Article  CAS  Google Scholar 

  2. U. Ticmanis, M. Kaiser, G. Pantel, et al., in Proceedings of the 35th International Annual Conference ICT (ICT, Karlsruhe, 2004), p. 70/1.

  3. G. M. Nazin, V. V. Dubikhin, T. K. Goncharov, A. I. Kazakov, A. V. Nabatova, and A. V. Shastin, Russ. J. Phys. Chem. B 15, 483 (2021).

    Article  CAS  Google Scholar 

  4. G. M. Nazin, V. V. Dubikhin, T. K. Goncharov, A. I. Kazakov, A. V. Nabatova and A. V. Shastin, Russ. J. Phys. Chem. B 15, 604 (2021).

    Article  CAS  Google Scholar 

  5. G. M. Nazin, V. V. Dubikhin, T. K. Goncharov, et al., Russ. J. Phys. Chem. B 16 (2022, in press).

  6. B. E. Krisyuk, V. V. Zakarov, N. V. Chukanov, et al., Centr. Eur. J. Energ. Mater. 17 (1), 20 (2020). https://doi.org/10.22211/cejem/118513

    Article  CAS  Google Scholar 

  7. N. N. Volkova, A. I. Kazakov, A. V. Danilchik, et al., in New Trends in Research of Energetic Materials, Proceedings of the 21st Seminar (Univ. Pardubice, Czech Republic, 2018), p. 1143.

  8. G. M. Nazin, V. V. Dubikhin, I. L. Dalinger, A. I. Kazakov, and A. V. Nabatova, Russ. J. Phys. Chem. B 15, 74 (2021).

    Article  CAS  Google Scholar 

  9. A. V. Shastin, B. L. Korsunskii, and V. P. Lodygina, Russ. J. Appl. Chem. 82, 1802 (2009). https://doi.org/10.1134/S1070427209100103

    Article  CAS  Google Scholar 

  10. M.-J. Crawford, J. Evans, M. Cöbel, et al., Propell. Explos. Pyrotech. 32, 478 (2007). https://doi.org/10.1002/prep.200700240

    Article  CAS  Google Scholar 

  11. K. Baum, S. S. Bigelow, N. V. Nguyen, et al., Org. Chem. 57, 235 (1992). https://doi.org/10.1021/jo00027a042

    Article  CAS  Google Scholar 

  12. B. E. Krisyuk, Russ. J. Phys. Chem. B 14, 1 (2020). https://doi.org/10.1134/S1990793120010054

    Article  CAS  Google Scholar 

  13. F. I. Dubovitskii, G. B. Manelis, and A. G. Merzhanov, Dokl. Akad. Nauk SSSR 121, 668 (1958).

    CAS  Google Scholar 

Download references

Funding

This study was funded by the Institute of Problems of Chemical Physics, Russian Academy of Sciences as part of government assignments (registration numbers АААА-А19-119101690058-9 and АААА-А19-119120690042-9).

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    G. M. Nazin, V. V. Dubikhin, A. I. Kazakov, A. V. Nabatova, B. E. Krisyuk, N. N. Volkova & A. V. Shastin

Authors
  1. G. M. Nazin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Dubikhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Kazakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Nabatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. B. E. Krisyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. N. Volkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. V. Shastin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. I. Kazakov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nazin, G.M., Dubikhin, V.V., Kazakov, A.I. et al. Kinetics of the Decomposition of 1,1-Diamino-2,2-Dinitroethylene (FOX-7). Part 4: Comparison of the Decomposition Reactions of FOX-7 and Its Diazacyclic Derivatives. Russ. J. Phys. Chem. B 16, 308–315 (2022). https://doi.org/10.1134/S1990793122020208

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793122020208

Keywords:

Search

Navigation