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Energy Production and Recovery of Rare Metals from Ash Residue During Coal Filtration Combustion

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Abstract

The results of studies on the extraction of vanadium, nickel, and cobalt compounds from ash residue obtained in the process of the filtration combustion of charcoal and brown coal with subsequent hydrometallurgical extraction of metals from ash residues are presented. Coals with metal salts preliminarily deposited on them are used for the research. The regularities of gasification of the studied coals (temperatures and combustion rates) are studied and it is shown that the heat of combustion of gaseous products for both types of coals is 4.3–4.5 MJ/m3. Using X-ray phase analysis, the crystal structures of metal compounds in ash residues are determined. Metal compounds are leached from the ash residue with water, acids, hydrogen peroxide, and their mixtures. It is established that vanadium compounds almost completely turn into a solution during leaching with acid solutions. At the same time, the maximum degree of extraction of nickel and cobalt from the ash residues of gasification does not exceed, respectively, 59 and 61% for charcoal and 40 and 28% for brown coal. This is due to the fact that nickel and cobalt compounds are present in ash residues, which are resistant to the action of aqueous solutions of acids and other oxidizing agents.

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Funding

The study was financially supported by the Russian Foundation for Basic Research as part of scientific project no. 18-29-24029-mk and state order no. 0089-2019-0018 (registration number АААА-А19-119-022690098-3). Part of the analyses was carried out on the equipment of the Analytical Center for Collective Use of the Institute of Problems of Chemical Physics, Russian Academy of Sciences and Institute of Petrochemical Synthesis, Russian Academy of Sciences.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    E. A. Salgansky, V. M. Kislov, M. V. Tsvetkov, A. Yu. Zaichenko, D. N. Podlesniy & M. V. Salganskaya

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    K. M. Kadiev, M. Ya. Visaliev & L. A. Zekel

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  1. E. A. Salgansky
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  2. V. M. Kislov
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  3. M. V. Tsvetkov
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  4. A. Yu. Zaichenko
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  5. D. N. Podlesniy
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  6. M. V. Salganskaya
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  8. M. Ya. Visaliev
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  9. L. A. Zekel
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Correspondence to M. V. Tsvetkov.

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Salgansky, E.A., Kislov, V.M., Tsvetkov, M.V. et al. Energy Production and Recovery of Rare Metals from Ash Residue During Coal Filtration Combustion. Russ. J. Phys. Chem. B 16, 268–277 (2022). https://doi.org/10.1134/S1990793122020105

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