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Dispersive Solid-Phase Extraction for Bromocresol Green Removal with β-Cyclodextrin Functionalized Magnetic Nanotubes

  • CHEMICAL PHYSICS OF NANO-MATERIALS
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Abstract

The present study introduced a new and fast method for the removal of trace amounts of bromocresol green in water samples using β-cyclodextrin functionalized magnetic nanotubes. The donor phase used in the method contains (aqueous phase with bromocresol green) and the acceptor phase (functionalized magnetic nanotubes with cyclodextrin). Experiments were performed in two steps of extraction of dye from aqueous sample and desorption of dye using ethanol. The analysis of the samples was carried out with a UV-Vis spectrophotometer. The parameters of dye extraction were studied such as the effect of solvents, pH of the phases, time of extraction, interference species, and elution solvent volumes. The isotherm of dye adsorption was well described by the Langmuir model, and the sorption capacity in the maximum was 34.18 mg g–1. The kinetic studies indicating adsorption of bromocresol green by Fe3O4@MWCNT/CD fitted with the pseudo-second-order kinetic model and resulting from that chemisorption process is the rate-limiting process in the bromocresol green adsorption. The limit of detection and limit of quantification factors for dye extraction were 7.2 and 23 µg L–1, respectively. A linear range was achieved between 1–10 mg L–1. In the last, the cyclodextrin functionalized magnetic nanotubes (Fe3O4@MWCNT/CD) presented a high potential for bromocresol green removal from aqueous samples.

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ACKNOWLEDGMENTS

The authors wish to thank the Islamic Azad University of Varamin-Pishva for the support of this research.

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Authors and Affiliations

  1. Department of Chemistry, Varamin-Pishva Branch, Islamic Azad University, Varamin, Iran

    Ali Moghimi

  2. Department of Resin and Additives, Institute for Color Science and Technology, Tehran, Iran

    Milad Abniki

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  1. Ali Moghimi
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  2. Milad Abniki
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Correspondence to Ali Moghimi.

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Ali Moghimi, Milad Abniki Dispersive Solid-Phase Extraction for Bromocresol Green Removal with β-Cyclodextrin Functionalized Magnetic Nanotubes. Russ. J. Phys. Chem. B 15 (Suppl 1), S130–S139 (2021). https://doi.org/10.1134/S1990793121090128

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  • DOI: https://doi.org/10.1134/S1990793121090128

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