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Solution of the Inverse Chemical Kinetics Problem According to Stationary Multi Experiments

  • KINETICS AND MECHANISM OF CHEMICAL REACTIONS, CATALYSIS
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Abstract

A method for solving the inverse problem of chemical kinetics based on the data of stationary experiments with different initial conditions (multiple experiments), taking into account the measurement errors in an isothermal gradientless reactor, is presented. Examples of using the method for determining the intervals of the physical values of the rate constants of the stages of multistage nonlinear reactions are given. The influence of the measurement errors on the accuracy and stability of the method is estimated.

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ACKNOWLEDGMENTS

The author thanks V.Kh. Fedotov for his helpful discussions of the study.

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Authors and Affiliations

  1. Ulyanov Chuvash State University, Ulyanova, Cheboksary, Russia

    N. I. Koltsov

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  1. N. I. Koltsov
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Koltsov, N.I. Solution of the Inverse Chemical Kinetics Problem According to Stationary Multi Experiments. Russ. J. Phys. Chem. B 15, 476–482 (2021). https://doi.org/10.1134/S1990793121030234

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  • DOI: https://doi.org/10.1134/S1990793121030234

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