Abstract
The effect of a small addition of Xe on the conditions for the occurrence of detonation in an incident shock wave (SW) with a change in its intensity is studied. The experiments are carried out in a shock tube (ST) with mixtures (75 – q)% H2 + 25% air + q% Xe, where q = 0, 0.25, and 0.5. The addition of Xe leads to a shift in the detonation threshold to the region where the conditions are more unfavorable for its occurrence. Moreover, decreasing x from 0.5 to 0.25 causes a stronger shift in the detonation threshold; i.e., dependence x became nonmonotonic. This effect is due to a strong increase in the frequency of high-energy collisions of O2 and Xe in the front compared to the equilibrium behind the wave and the subsequent significant acceleration of the chemical interaction of O2 and H2 behind the front. It is a consequence of the occurrence of a specific translational nonequilibrium in the wave front. This is indicated by the results of similar studies of the effect of replacing a small amount with an inappropriate amount of Xe on the conditions for the onset of detonation for mixtures of 10% H2 + 5% O2 + 85% He. In addition, the results of the performed numerical simulation with mixtures (75 – q)% H2 + 25% air + q% Xe (q = 0.25, 0.5), taking into account the rotational relaxation of О2 and N2 for conditions close to the conditions of the aforementioned experiments, showed the possibility of a nonmonotonic shift of the detonation threshold.
Similar content being viewed by others
REFERENCES
V. V. Azatyan, V. M. Prokopenko, N. V. Chapysheva, and K. S. Abramov, Russ. J. Phys. Chem. B 12, 103 (2018).
A. M. Tereza and E. K. Anderzhanov, Russ. J. Phys. Chem. B 13, 626 (2019).
P. A. Vlasov, T. S. Demidenko, V. N. Smirnov, A. M. Tereza, and E. V. Atkin, Russ. J. Phys. Chem. B 10, 983 (2016).
T. V. Bazhenova, A. V. Emelianov, A. V. Eremin, and V. Y. Velicodny, in Proceedings of the International Symposia on Shock Waves ISSW-21, Ed. by A. Howling (Great Keppel, Australia, 1998), p. 195.
V. Yu. Velikodnyi, A. V. Emel’yanov, and A. V. Eremin, Tech. Phys. 44, 1150 (1999).
A. V. Emelianov, A. V. Eremin, and S. V. Kulikov, Tech. Phys. 58, 647 (2013).
O. G. Divakov, A. V. Eremin, V. S. Ziborov, and V. E. Fortov, Dokl. Akad. Nauk 373, 487 (2000).
V. Yu. Velikodnyi and V. A. Bityurin, Khim. Fiz. 16 (9), 14 (1997).
S. V. Kulikov and G. B. Manelis, Dokl. Chem. 382, 29 (2002).
S. V. Kulikov, G. B. Manelis, and O. N. Ternovaya, Russ. J. Phys. Chem. B 1, 250 (2007).
S. V. Kulikov and N. A. Chervonnaya, Russ. J. Phys. Chem. B 12, 98 (2018).
O. I. Dodulat, Yu. Yu. Kloss, and F. G. Cheremisin, Fiz.-Khim. Kinet. Gaz. Din. 14 (1) (2013). http://www.chemphys.edu.ru.
Shock Pipes, Collection of Articles, Ed. by Kh. A. Rakhmatullin and S. S. Semenov (Inostr. Liter., Moscow, 1962) [in Russian].
Ya. B. Zel’dovich, A. P. Genich, and G. B. Manelis, Sov. Phys. Dokl. 24, 756 (1979).
C. V. Kulikov, Shock Waves 7, 25 (1997).
G. Bird, Molecular Gas Dynamics and the Direct Simulation of Gas Flows (Clarendon, Oxford, 1994).
S. V. Kulikov and P. K. Berzigiyarov, Vychisl. Metody Program. 3 (2), 51 (2002).
A. P. Genich, S. V. Kulikov, G. B. Manelis, V. V. Serikov, and V. E. Yanitskii, Zh. Vychisl. Mat. Mat. Fiz. 26, 1839 (1986).
A. Gaydon and I. Hurle, The Shock Tube in High-Temperature Chemical Physics (Chapman and Hall, London, 1963).
A. V. Bogdanov, G. V. Dubrovskii, A. I. Osipov, and V. M. Strel’chenya, Rotational Relaxation in Gases and Plasma (Energoatomizdat, Moscow, 1991) [in Russian].
S. V. Kulikov, Mat. Model. 11 (3), 96 (1999).
ACKNOWLEDGMENTS
The authors thank the Interdepartmental Supercomputer Center of the Russian Academy of Sciences for providing the computing resources. The authors also thank Yu.P. Myagkov for his help with the experiments and O.N. Ternovaya for her help in processing the calculation results and in carrying out the experiments.
Funding
The study was carried out on the topics of state assignments (registration nos. 0089-2014-0018 and 0089-2019-0017).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Atanov, G.A., Ezhov, V.M., Kulikov, S.V. et al. Dependence of the Knock Threshold of an H2-Air Mixture With Small Xe Additives. Russ. J. Phys. Chem. B 15, 250–258 (2021). https://doi.org/10.1134/S1990793121020032
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1990793121020032