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Oxidation of Acetic Acid by Hydrogen Peroxide in the Aqueous Medium in Supercritical Fluid Conditions

Abstract—The oxidation of acetic acid (AA) in its 10% aqueous solution at 673–748 K and 25 MPa is studied in periodic and continuous regimes. Hydrogen peroxide is used as an oxidant. The degree of AA conversion is determined based on the oxygen chemical consumption index.

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Fig. 1.


  1. 1

    S. E. Alekseev, Extended Abstract of Cand. Sci. (Tech. Sci.) Dissertation (Moscow, 2006).

  2. 2

    K. Chin, Chem. Eng. (U.S.A.), No. 7, 39 (1997).

  3. 3

    S. B. Rinehimer, Water Cond. Purif., No. 8, 92 (1995).

  4. 4

    E. S. Gayazova, R. A. Usmanov, F. M. Gumerov, S. V. Friedland, Z. I. Zaripov, F. R. Gabitov, and R. Z. Musin, J. Anal. Mass Spectrom. Chromatogr., No. 1, 48 (2013).

  5. 5

    X. Xiaowu and S. Shi-gun, Hefai Uniu. Technol. Natur. Sci., No. 3, 270 (2005).

  6. 6

    C. Jian-guo, L. Ai-min, and Z. Quan-xing, Hefai Uniu. Sci., No. 3, 326 (2004).

  7. 7

    R. A. Usmanov, R. R. Gabitov, Sh. A. Biktashev, F. N. Shamsetdinov, F. M. Gumerov, F. R. Gabitov, Z. I. Zaripov, R. A. Gazizov, R. S. Yarullin, and I. A. Yakushev, Russ. J. Phys. Chem. B 5, 1216 (2011).

    CAS  Article  Google Scholar 

  8. 8

    F. M. Gumerov, R. A. Kayumov, R. A. Usmanov, A. A. Sagdeev, I. Sh. Abdullin, and R. F. Sharafeev, Am. J. Anal. Chem. 3, 950 (2012).

    Article  Google Scholar 

  9. 9

    O. N. Fedyaeva and A. A. Vostrikov, Russ. J. Phys. Chem. B 6, 844 (2012).

    CAS  Article  Google Scholar 

  10. 10

    P. K. Savage and M. A. Smith, Environ. Sci. Technol. 29, 216 (1995).

    CAS  Article  Google Scholar 

  11. 11

    T. J. Wightman, PhD Thesis (Univ. of California, Berkeley, 1981).

  12. 12

    L. Li, P. Chen, and E. F. Glayna, AIChE J. 37, 1687 (1991).

    CAS  Article  Google Scholar 

  13. 13

    L. T. Boock and M. T. Klein, Ind. Eng. Chem. Res. 32, 2464 (1993).

    CAS  Article  Google Scholar 

  14. 14

    S. E. Rice, R. R. Steeper, and C. A. LaJeunesse, Sandia Report SAND94-8203 UC-402, p. 1993.

  15. 15

    D. Lee, E. E. Gloyna, L. Li, and J. Lee, Supercrit. Fluids 3, 249 (1990).

    Article  Google Scholar 

  16. 16

    R. A. Kayumov, A. A. Sagdeev, and F. M. Gumerov, Utilization of Molybdenum-Containing Waste Using Supercritical Fluid Media (Brig, Kazan’, 2016) [in Russian].

  17. 17

    F. M. Gumerov, R. A. Usmanov, A. U. Aetov, I. R. Gabitov, R. R. Gabitov, Z. I. Zaripov, and S. V. Mazanov, Mass Spectrom. Purif. Tech. 3 (1), 1 (2017).

    Google Scholar 

  18. 18

    P. Usmanov, R. Gabitov, L. Miftakhova, and F. Gumerov, Vestn. Kazan. Tekhnol. Univ. 17, 244 (2013).

    Google Scholar 

  19. 19

    A. Aetov, R. Usmanov, R. Gabitov, S. Mazanov, and M. Kurbangeleev, Vestn. Kazan. Tekhnol. Univ. 19, 37 (2016).

    CAS  Google Scholar 

  20. 20

    M. Gonikberg, Chemical Equilibrium and Reaction Rate at High Pressures (Khimiya, Moscow, 1969) [in Russian].

    Google Scholar 

  21. 21

    P. A. Webley and J. W. Tester, in Supercritical Fluid Science and Technology, Ed. by K. P. Johnston and J. M. L. Penninger, Vol. 406 of ACS Symp. Ser. (Am. Chem. Soc., Washington, DC, 1989), p. 259.

  22. 22

    H. R. Holgate, Combust. Sci. Technol., No. 88, 369 (1993).

  23. 23

    J. S. Meyer, Ph. A. Marmne, and J. W. Tester, AIChE J. 41, 2108 (1995).

    CAS  Article  Google Scholar 

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This work was supported by Russian Foundation for Basic Research (project no. 18-29-06041_mk).

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Correspondence to A. U. Aetov.

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Translated by L. Mosina

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Mazanov, S.V., Aetov, A.U., Usmanov, R.A. et al. Oxidation of Acetic Acid by Hydrogen Peroxide in the Aqueous Medium in Supercritical Fluid Conditions. Russ. J. Phys. Chem. B 13, 1131–1134 (2019).

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  • supercritical water oxidation
  • acetic acid
  • pH
  • oxygen chemical consumption index