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Initiator Based on the Cu(II) and Cetyl Trimethyl Ammonium Bromide Compounds that Generates Free Radicals in the Decomposition of tert-Butyl Hydroperoxide in Optimum Temperature Conditions

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Abstract

The two-component composition consisting of complex copper Cu(II) compounds and cationic surface-activated substance cetyl trimethyl ammonium bromide (CTAB) exhibits high catalytic reactivity during decomposition of tert-butyl hydroperoxide. One specific characteristic of the effects of the Cu(II) + CTAB binary system consists in its high rate of processing without visible signs of deactivation in the transformation of significant amounts of the reagent in optimum temperature conditions.

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Funding

This study was carried out under the government contract of Federal Agency for Scientific Organizations of Russia (0082-2018-0006, no. AAAA-A18-118020890097-1).

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics of Russian Academy of Sciences, Moscow, Russia

    L. A. Smurova & Z. S. Kartasheva

Authors
  1. L. A. Smurova
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  2. Z. S. Kartasheva
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Correspondence to L. A. Smurova.

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Translated by G. Levina

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Smurova, L.A., Kartasheva, Z.S. Initiator Based on the Cu(II) and Cetyl Trimethyl Ammonium Bromide Compounds that Generates Free Radicals in the Decomposition of tert-Butyl Hydroperoxide in Optimum Temperature Conditions. Russ. J. Phys. Chem. B 13, 554–556 (2019). https://doi.org/10.1134/S1990793119030126

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  • DOI: https://doi.org/10.1134/S1990793119030126

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