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Study of Side Reactions in the Ozonolysis of Organic Compounds in a Barbotage Reactor

  • KINETICS AND MECHANISM OF CHEMICAL REACTIONS. CATALYSIS
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Abstract

The kinetics of the ozonolysis of unsaturated hydrocarbons in a flow-type barbotage reactor with the use of tetrachloromethane as the solvent is investigated. It is found that a side reaction of ozone with the solvent which has the first order with respect to ozone proceeds in the system. It follows from the comparison of the theoretical and experimental data that this reaction does not affect the measurement of the amount of ozone consumed for the ozonolysis of the specimen per se. It is concluded that the side reaction proceeds at a stage preceding the interaction of ozone with unsaturated hydrocarbons in the liquid phase of the reactor.

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FUNDING

This work was financially supported by the Program of Basic Research no. 46.15 of the Semenov Institute of Chemical Physics, Russian Academy of Sciences. The project number at the Federal Agency for Scientific Organizations is 0082-2014-0005. The state registration number at the Center for Information Technology and Executive Branches is AAAA-A17-117091220076-4.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    N. G. Taganov, V. G. Fedotov & T. V. Grinevich

Authors
  1. N. G. Taganov
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  2. V. G. Fedotov
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  3. T. V. Grinevich
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Correspondence to N. G. Taganov.

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Translated by E. Boltukhina

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Taganov, N.G., Fedotov, V.G. & Grinevich, T.V. Study of Side Reactions in the Ozonolysis of Organic Compounds in a Barbotage Reactor. Russ. J. Phys. Chem. B 13, 458–463 (2019). https://doi.org/10.1134/S1990793119020234

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  • DOI: https://doi.org/10.1134/S1990793119020234

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