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Russian Journal of Physical Chemistry B

, Volume 13, Issue 1, pp 68–74 | Cite as

A Study of the Regularities of the Solid-Phase Synthesis of Metal Stearates

  • A. A. MomziakovEmail author
  • A. A. Zharov
  • K. S. Fadeeva
  • T. R. Deberdeev
  • A. A. Berlin
  • R. Y. Deberdeev
Kinetics and Mechanism of Chemical Reactions Catalysis
  • 6 Downloads

Abstract

Features of the solid-phase synthesis of metal stearates (calcium, barium, zinc, and silver stearates) on a Bridgman anvil-type device were studied. Factors of the solid-phase reaction between reagents were determined. The activation volumes of the reactions between stearic acid with calcium oxide and silver oxide were determined. The initial rates of the solid-phase synthesis of silver and calcium stearate were calculated. The rates of synthesis of metal stearates in liquid and solid phases were compared. The data showed that metal carboxylates could be synthesized in a solution-less medium.

Keywords

solid-phase synthesis Bridgman anvil calcium stearate zinc stearate silver stearate manganese stearate barium stearate 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. A. Momziakov
    • 1
    Email author
  • A. A. Zharov
    • 2
  • K. S. Fadeeva
    • 1
  • T. R. Deberdeev
    • 1
  • A. A. Berlin
    • 3
  • R. Y. Deberdeev
    • 1
  1. 1.Kazan National Research Technological UniversityKazan, Republic of TatarstanRussia
  2. 2.Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia

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