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Atomic and Electronic Structure and Chemical Properties of Coatings Based on Gold and Nickel Nanoparticles Deposited on Graphite

  • Kinetics and Mechanism of Chemical Reactions Catalysis
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Abstract

The results of a study of the interaction of H2, O2, and CO with single nanoparticles of gold and oxidized nickel forming a two-component coating on graphite are given. It is established that hydrogen and carbon monoxide may form HCO particles on the surface of gold and not on the surface of nickel, and these particles are able later to migrate and be adsorbed on nickel nanoparticles. Oxygen mainly oxidizes those HCO particles, which are associated with gold. Among the products of reactions of the above listed gases, H2O and CO2 molecules are also detected.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    M. V. Grishin, A. K. Gatin, N. V. Dokhlikova, N. N. Kolchenko, S. Yu. Sarvadii & B. R. Shub

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  1. M. V. Grishin
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  2. A. K. Gatin
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  3. N. V. Dokhlikova
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  4. N. N. Kolchenko
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  5. S. Yu. Sarvadii
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  6. B. R. Shub
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Correspondence to M. V. Grishin.

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Grishin, M.V., Gatin, A.K., Dokhlikova, N.V. et al. Atomic and Electronic Structure and Chemical Properties of Coatings Based on Gold and Nickel Nanoparticles Deposited on Graphite. Russ. J. Phys. Chem. B 13, 9–15 (2019). https://doi.org/10.1134/S1990793118060167

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  • DOI: https://doi.org/10.1134/S1990793118060167

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