Abstract
A mathematical model of the physicochemical processes that occur under low-frequency mechanical action on bimolecular reaction kinetics with consideration for the association of reagents is presented. As a result of the mathematical simulation, special features of the kinetics and stability of the reaction modes were established. It was shown that, in a structured liquid, a formally simple reaction occurs as a complex process with the appearance of bistability regimes, the formation of a temporal dissipative structure, and the complex structure of intermediate concentration oscillations. The possibility of controlling transitions from stable to unstable reaction conditions and vice versa under changes in the external action amplitude was demonstrated.
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Original Russian Text © T.P. Kulagina, L.P. Smirnov, Z.S. Andrianova, 2018, published in Khimicheskaya Fizika, 2018, Vol. 37, No. 7, pp. 19–25.
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Kulagina, T.P., Smirnov, L.P. & Andrianova, Z.S. Mathematical Simulation of Low-Frequency Mechanical Action on Bimolecular Reaction Kinetics in a Structured Liquid. Russ. J. Phys. Chem. B 12, 657–662 (2018). https://doi.org/10.1134/S1990793118040139
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DOI: https://doi.org/10.1134/S1990793118040139