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A Detailed Kinetic Mechanism of Multistage Oxidation and Combustion of Octanes

  • Combustion, Explosion, and Shock Waves
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Abstract

This study has been focused on the construction of a generalized detailed kinetic mechanism of oxidation and combustion of isoheptane and isooctanes (2-methylhexane, 2-methylheptane, 2,2-dimethylhexane, and 2,2,4-trimethylpentane) to describe both high-temperature reactions and the low-temperature multistage process with separated stages of “cool,” “blue,” and “hot” flames. In accordance with the proposed mechanism, a numerical simulation of autoignition and flame propagation in homogeneous fuel–air mixtures and liquid droplet combustion has been conducted; the calculation results have been compared with the experimental data. Satisfactory qualitative and quantitative agreement of the calculation and experimental results has been obtained.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    V. Ya. Basevich, A. A. Belyaev, S. N. Medvedev, S. M. Frolov & F. S. Frolov

  2. National Research Nuclear University Moscow Engineering Physics Institute, Moscow, Russia

    S. M. Frolov

  3. Scientific Research Institute of System Development, Russian Academy of Sciences, Moscow, Russia

    S. M. Frolov & F. S. Frolov

Authors
  1. V. Ya. Basevich
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  2. A. A. Belyaev
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  3. S. N. Medvedev
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  4. S. M. Frolov
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  5. F. S. Frolov
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Corresponding author

Correspondence to S. M. Frolov.

Additional information

Original Russian Text © V.Ya. Basevich, A.A. Belyaev, S.N. Medvedev, S.M. Frolov, F.S. Frolov, 2018, published in Khimicheskaya Fizika, 2018, Vol. 37, No. 6, pp. 44–54.

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Basevich, V.Y., Belyaev, A.A., Medvedev, S.N. et al. A Detailed Kinetic Mechanism of Multistage Oxidation and Combustion of Octanes. Russ. J. Phys. Chem. B 12, 448–457 (2018). https://doi.org/10.1134/S1990793118030223

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  • DOI: https://doi.org/10.1134/S1990793118030223

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