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Influence of the Solvent on the Formation of CNR/BNR Polymer Blends

  • Chemical Physics of Polymer Materials
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Abstract

Structural dynamic analysis combining IR spectroscopy, DSC, and EPR spectroscopy is applied to studying films based on chlorinated natural rubber (CNR), butadiene nitrile rubber (BNR), and blends thereof. The influence of various solvents, such as methyl ethyl ketone (MEK), ethyl acetate (EA), methyl acetate (MA), and acetone (A), on the structure and molecular dynamics (τ) of CNR/BNR polymer films is examined. The strongest changes in the molecular mobility (τ) and the glass transition temperature (Tgt) relative to those of the starting materials are observed for the 50: 50% CNR/BNR blends prepared using all the solvents (except for acetone, the maximum values of τ for which is observed at a ratio of CNR: BNR = 80: 20%), which can be explained by the inversion of phases in the blends. Annealing at 140°С causes an increase in the correlation time of the probe, and, consequently, a decrease in the molecular mobility, which is due to the intermolecular crosslinking of the components.

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References

  1. M. Yu. Nebratenko, Yu. A. Naumova, and Yu. N. Filatov, Vestn. MITKhT 3 (3), 31 (2008).

    Google Scholar 

  2. S. P. Papkov, Physicochemical Principles of Polymer Solution Processing (Khimiya, Moscow, 1971) [in Russian].

    Google Scholar 

  3. L. R. Lyusova, L. S. Krokhina, A. V. Filimonov, et al., Kauch. Rezina, No. 2, 47 (1995).

    Google Scholar 

  4. S. G. Karpova, Yu. A. Naumova, Yu. K. Lukanina, S. S. Groshanova, L. P. Lyusova, and A. A. Popov, Russ. J. Phys. Chem. B 8, 403 (2014).

    Article  CAS  Google Scholar 

  5. M. P. Zverev, Vysokomol. Soedin., Ser. A 16, 511 (1974).

    CAS  Google Scholar 

  6. E. F. Mironova, A. N. Kondrat’ev, and I. A. Tutorskii, Prom-st’ SK, Shin RTI, No. 6, 12 (1989).

    Google Scholar 

  7. I. V. Kalashnikova, S. V. Kotova, L. R. Lyusova, et al., in Proceedings of the 7th Annual Youth Conference of IBKhF RAN-VUZY on Biochemical Physics (IBKhF RAN im. N. M. Emanuelya, Moscow, 2007), p.135.

    Google Scholar 

  8. A. A. Berlin, V. I. Ganina, V. A. Kargin, et al., Vysokomol. Soedin., Ser. A 6, 1684 (1964).

    CAS  Google Scholar 

  9. S. V. Kotova, Cand. Sci. (Tech. Sci.) Dissertation (Mosc. Inst. Fine Chem. Technol., Moscow, 2009).

    Google Scholar 

  10. D. E. Budil, S. Lee, S. Saxena, and J. H. Freed, J. Magn. Res. A 120, 155 (1996).

    Article  CAS  Google Scholar 

  11. V. P. Timofeev, A. Yu. Misharin, and Ya. V. Tkachev, Biophysics 56, 407 (2011).

    Article  Google Scholar 

  12. A. M. Vasserman and A. L. Kovarskii, Spin Labels and Probes in Physical Chemistry of Polymers (Nauka, Moscow, 1986) [in Russian].

    Google Scholar 

  13. M. Ratzsch, G. Haudel, G. Pompe, and E. Meyer, J. Macromol. Sci., Part A 27, 1631 (1990).

    Google Scholar 

  14. M. Yu. Boksha, Cand. Sci. (Tech. Sci.) Dissertation (Mosc. Inst. Fine Chem. Technol., Moscow, 2010).

    Google Scholar 

  15. S. G. Karpova, Yu. A. Naumova, L. R. Lyusova, E. L. Khmeleva, and A. A. Popov, Polym. Sci., Ser. A 57, 330 (2015).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    S. G. Karpova

  2. Moscow Technological University (Institute of Fine Chemical Technologies), Moscow, 119571, Russia

    E. G. Milyushkina, L. R. Lusova & Yu. A. Naumova

  3. Plekhanov Russian Economic University, Moscow, 117997, Russia

    A. A. Popov

Authors
  1. S. G. Karpova
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  2. E. G. Milyushkina
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  3. L. R. Lusova
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  4. Yu. A. Naumova
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  5. A. A. Popov
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Correspondence to S. G. Karpova.

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Original Russian Text © S.G. Karpova, E.G. Milyushkina, L.R. Lusova, Yu.A. Naumova, A.A. Popov, 2018, published in Khimicheskaya Fizika, 2018, Vol. 37, No. 3, pp. 39–46.

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Karpova, S.G., Milyushkina, E.G., Lusova, L.R. et al. Influence of the Solvent on the Formation of CNR/BNR Polymer Blends. Russ. J. Phys. Chem. B 12, 285–292 (2018). https://doi.org/10.1134/S1990793118020070

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  • DOI: https://doi.org/10.1134/S1990793118020070

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