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Hybrid Biodegradable Nanocomposites Based on a Biopolyester Matrix and Magnetic Iron Oxide Nanoparticles: Structural, Magnetic, and Electronic Characteristics

  • Chemical Physics of Nanomaterials
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Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

The structural, electronic, and magnetic properties of iron oxide nanoparticles encapsulated in hybrid biodegradable therapeutic systems based on poly-3-hydroxybutyrate and chitosan are comprehensively studied using Mössbauer spectroscopy, X-ray diffraction, small-angle X-ray scattering, and macroscopic magnetization measurements. It is shown that iron oxide in concentrations of 4 and 8 wt % in the polymer matrix of magnetically isotropic and magnetoanisotropic systems exists in the form of nanosized (d ≈ 7–8 nm) superparamagnetic clusters. Iron oxide clusters have the structure of a nonstoichiometric inverse spinel, intermediate between polymorphous modifications of Fe3O4 and γ-Fe2O3.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. E. Prusakov, Yu. V. Maksimov, Yu. F. Krupyanskii, A. V. Bychkova, A. L. Iordanskii & A. A. Berlin

  2. Ogarev Mordova State University, Saransk, 430005, Russia

    K. N. Nishchev, A. V. Golub’ev & V. I. Beglov

  3. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    A. V. Bychkova

Authors
  1. V. E. Prusakov
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  2. Yu. V. Maksimov
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  3. K. N. Nishchev
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  4. A. V. Golub’ev
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  5. V. I. Beglov
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  6. Yu. F. Krupyanskii
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  7. A. V. Bychkova
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  8. A. L. Iordanskii
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  9. A. A. Berlin
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Correspondence to V. E. Prusakov.

Additional information

Original Russian Text © V.E. Prusakov, Yu.V. Maksimov, K.N. Nishchev, A.V. Golub’ev, V.I. Beglov, Yu.F. Krupyanskii, A.V. Bychkova, A.L. Iordanskii, A.A. Berlin, 2018, published in Khimicheskaya Fizika, 2018, Vol. 37, No. 1, pp. 83–90.

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Prusakov, V.E., Maksimov, Y.V., Nishchev, K.N. et al. Hybrid Biodegradable Nanocomposites Based on a Biopolyester Matrix and Magnetic Iron Oxide Nanoparticles: Structural, Magnetic, and Electronic Characteristics. Russ. J. Phys. Chem. B 12, 158–164 (2018). https://doi.org/10.1134/S1990793118010116

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  • DOI: https://doi.org/10.1134/S1990793118010116

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