Abstract
The thermal modes of a flow plug reactor with an exothermic chemical reaction are numerically simulated. A heterogeneous reaction system consisting of two immiscible liquids is studied: one of the liquids (dispersed phase) in the form of droplets is distributed in the other (dispersion phase). The characteristics of the thermal modes of the reactor at various values of two governing parameters, the Damköhler number and the rate of extraction of the dissolved substance from the dispersed phase into the dispersion phase is examined. Two modes of chemical reaction in the reactor are demonstrated to be possible: low-temperature and high-temperature. Critical criteria of thermal ignition are formulated. The dependence of the structure of the thermal wave on the governing parameters is investigated.
Similar content being viewed by others
References
A. S. Evenchik and V. A. Makhlin, Teor. Osn. Khim. Tekhnol. 25, 828 (1991).
E. N. Shatunova, D. A. Vaganov, and A. A. Butakov, Teor. Osn. Khim. Tekhnol. 28, 145 (1994).
S. Feyo de Azevedo and A. P. Wardle, Chem. Eng. Sci. 44, 2311 (1989).
S. S. Tambe, S. R. Inamdar, J. K. Bandopadhyay, et al., Chem. Eng. J. 46, 23 (1991).
V. R. Khandavalli, V. D. Rao, M. V. Ramakanth, et al., Chem. Eng. Sci. 48, 3677 (1993).
S. Ungureanu, C. Petrila, A. Mares, et al., Chem. Eng. Sci. 49, 1015 (1994).
C. A. Bostandzhiyan and K. G. Shkadinskii, Theor. Found. Chem. Eng. 44, 119 (2010).
A. G. Merzhanov and A. A. Butakov, in Proceedings of the International School-Seminar on Current Problems of Heat- and Mass Exchange in Chemical Technology (Akad. Nauk BSSR, Minsk, 1987), Part 3, p. 23.
R. M. Zaidel’ and Ya. B. Zel’dovich, Prikl. Mekh. Tekh. Fiz., No. 4, 27 (1962).
E. I. Maksimov, N. I. Peregudov, and A. A. Butakov, Fiz. Goreniya Vzryva 11, 568 (1975).
M. G. Slin’ko, Kinet. Katal. 1, 153 (1960).
C. van Heerden, Ind. Eng. Chem. 45, 1242 (1953).
V. Hlavaček and H. Hofman, Chem. Eng. Sci. 25, 173 (1970).
V. Hlavaček and H. Hofman, Chem. Eng. Sci. 25, 187 (1970).
L. R. Raymond and N. R. Amundson, Can. J. Chem. Eng. 42, 173 (1964).
E. A. Ivanov, V. S. Beskov, and M. G. Slin’ko, Teor. Osn. Khim. Tekhnol. 1, 488 (1967).
G. A. Aksel’rud and A. D. Molchanov, Dissolution of Solids (Khimiya, Moscow, 1977) [in Russian].
N. G. Samoilenko, V. A. Bostandgian, Yu. N. Finaeva, L. V. Kustova, and B. L. Korsounskii, Russ. J. Phys. Chem. B 9, 926 (2015).
V. A. Bostandzhiyan, Handbook of Statistical Distributions (Inst. Prikl. Khim. Fiz. RAN, Chernogolovka, 2013) [in Russian].
A. G. Merzhanov and A. K. Filonenko, Dokl. Akad. Nauk SSSR 152, 143 (1963).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.G. Samoilenko, E.N. Shatunova, V.A. Bostandzhiyan, B.L. Korsunskii, 2017, published in Khimicheskaya Fizika, 2017, Vol. 36, No. 9, pp. 32–39.
Rights and permissions
About this article
Cite this article
Samoilenko, N.G., Shatunova, E.N., Bostandzhiyan, V.A. et al. Thermal modes of a plug flow reactor with a liquid–liquid heterogeneous system. Russ. J. Phys. Chem. B 11, 808–814 (2017). https://doi.org/10.1134/S1990793117050104
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1990793117050104