Abstract
It is shown that the initiated oxidation of deuterated esters of linoleic acid proceeds as a radical chain process. The value of the kinetic isotope effect for hydrogen atom abstraction from the bisallyl group of linoleic acid esters is determined: 3.0 for tert-butyl peroxy and cumylperoxy radicals.
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Original Russian Text © I.V. Tikhonov, I.V. Moskalenko, E.M. Pliss, M.A. Fomich, A.V. Bekish, V.V. Shmanai, 2017, published in Khimicheskaya Fizika, 2017, Vol. 36, No. 5, pp. 14–18.
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Tikhonov, I.V., Moskalenko, I.V., Pliss, E.M. et al. Kinetic isotope H/D effect in the oxidation of ethers of linoleic acid in solutions. Russ. J. Phys. Chem. B 11, 395–399 (2017). https://doi.org/10.1134/S1990793117030113
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DOI: https://doi.org/10.1134/S1990793117030113