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Dynamic adsorption of nitrogen dioxide on zeolites

  • Chemical Physics of Ecological Processes
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Abstract

The dynamic adsorption of nitrogen dioxide on Zeolon 900H, Zeolon 900K, Zeolon 900Na, Zeolon 200H, Zeolon 500H, H/ZSM-5, Na/ZSM-5, and CaA zeolites is studied. Breakthrough curves C/C0 = σ(t) (C 0 is the initial concentration of NO2 at the adsorption column inlet and C is the breakthrough concentration at the column outlet) is measured over a temperature range of 290–430 K. It has been shown that the time dependence of C/C 0 is described by the Wheeler–Jonas equation. The parameters of this equation, the adsorption constant rate k v and dynamic adsorption capacity (DAC) are determined by fitting the theoretical curves to the experimental data for the aforementioned zeolites at 290–430 K. The Hertz–Knudsen equation is used to obtain theoretical temperature dependence of k v. For this dependence, the curve fitting method is also used to determine the adsorption activation energy E ad. It is found that the activation energy ranges within 300–500 cal/mol, which shows that the adsorption of NO2 on these zeolites is a physical process, with the electronic structure of the molecules being perturbed only slightly during the adsorption process. A theoretical formula for calculating the time of protective action of the sorbent is derived. It is shown that the DAC and the corresponding protective action time for the studied sorbents depend on the temperature and increase in the series Zeolon 900Na < Na/ZSM-5 < Zeolon 900K < H/ZSM-5 < Zeolon 500H < Zeolon 200H < Zeolon 900H for gas mask filters at room temperature (293 K), and increase in the series CaA < H/ZSM-5 < Zeolon 900H < Zeolon 500H < Na/ZSM-5 < Zeolon 200H < Zeolon 900K < Zeolon 900Na for systems of purification of flue gases from thermal power plants at 350 K.

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References

  1. Yu. S. Khodakov, Nitrogen Oxides and Heat and Power Engineering. Problems and Solutions, 2nd ed. (EST-M, Moscow, 2001) [in Russian].

    Google Scholar 

  2. M. J. Khinkis, I. K. Rabovitser, and M. J. Roberts, US Patent No. 5937772 (1999). http://www.freepatentsonline. com/5937772.pdf.

    Google Scholar 

  3. H. Sarv, US Patent No. 7491055 (2009). http://www.freepatentsonline.com/7491055.pdf.

    Google Scholar 

  4. A. I. Rodionov, V. N. Klushin, and N. S. Torocheshnikov, Environmental Protection Techniques, A Textbook for Higher Education, 2nd ed. (Khimiya, Moscow, 1989) [in Russian].

    Google Scholar 

  5. A. Doring and K. Richter, US Patent No. 7984609 (2011). http://www.freepatentsonline.com/7984609.pdf.

    Google Scholar 

  6. Y. Yamashita, D. Oki, M. H. Tran, and T. Sato, US Patent No. 8679412 (2014). http://www.freepatentsonline. com/8679412.pdf.

    Google Scholar 

  7. S. Nojima, K. Iida, Y. Obayashi, M. Kiyosawa, and M. Demoto, US Patent No. 8852518 (2014). http://www. freepatentsonline.com/8852518.pdf.

    Google Scholar 

  8. R. Quinn, US Patent No. 5797979 (1998). http://www. freepatentsonline.com/5797979.pdf.

    Google Scholar 

  9. L. Ding, D. E. Adamek, A. J. Dallas, et al., US Patent No. 2005/0092176 (2005). http://www.freepatentsonline. com/20050092176.pdf.

    Google Scholar 

  10. L. E. Hakka and M. A. Ouimet, US Patent No. 2003/0026744 (2003). http://www.freepatentsonline.com/20030026744.pdf.

    Google Scholar 

  11. I. V. Kumpanenko, A. V. Roshchin, N. A. Ivanova, I. D. Epinat’ev, A. M. Skryl’nikov, et al., Khim. Fiz. 35 (9), 20 (2016).

    Google Scholar 

  12. P. Markt and E. R. Schmid, J. Chromatogr. Libr. 2, 45 (1975).

    Article  Google Scholar 

  13. L. A. Jonas and J. A. Rehrmann, Carbon 11, 59 (1973).

    Article  CAS  Google Scholar 

  14. A. Wheeler and A. J. Robell, J. Catal. 13, 299 (1969).

    Article  CAS  Google Scholar 

  15. L. A. Jonas and W. J. Sevirbely, J. Catal. 24, 446 (1972).

    Article  CAS  Google Scholar 

  16. H. C. Thomas, J. Am. Chem. Soc. 66, 1664 (1944).

    Article  CAS  Google Scholar 

  17. Y. H. Yoon and J. H. Nelson, Am. Ind. Hyg. Assoc. J. 45, 509 (1984).

    Article  CAS  Google Scholar 

  18. Z. Xu, J.-G. Cai, and B.-C. Pan, J. Zhejiang Univ., Sci., A 14, 155 (2013).

    Article  CAS  Google Scholar 

  19. A. Ghribi and M. Chlendi, Asian J. Textile 1, 161 (2011).

    Article  Google Scholar 

  20. P. Lodewyckx and E. F. Vansant, Carbon 60, 612 (1999).

    CAS  Google Scholar 

  21. P. Lodewyckx, G. O. Wood, and S. K. Ryu, Carbon 42, 1351 (2004).

    Article  CAS  Google Scholar 

  22. N. M. Osmond and P. L. Phillips, Am. Ind. Hyg. Assoc. J. 62, 288 (2001).

    CAS  Google Scholar 

  23. Y. Fu, Cand. Sci. (Chem.) Dissertation (West Virginia Univ., Morgantown, 2003).

    Google Scholar 

  24. G. Grévillot, S. Marsteau, and C. Vallieres, J. Occup. Environ. Hyg. 8, 279 (2011).

    Article  Google Scholar 

  25. H. Ringel, in Proceedings of the 17th DOE Nuclear Air Cleaning Conference, Denver, Colorado, Aug. 2–5, 1983, p. 664. http://www.iaea.org/inis/collection/NCLCollectionStore/_ Public/14/795/14795769.pdf.

    Google Scholar 

  26. W. M. Davis and C. E. Dykstra, Physical Chemistry, A Modern Introduction (CRC, Taylor Francis Group, Boca Raton, FL, 2012), p. 404. www.crcpress.com/Physical-Chemistry-A-Modern-Introduction-Second-Edition/Davis/p/book/9781439810774.

    Google Scholar 

  27. H. Wise and J. Oudar, Material Concepts in Surface Reactivity and Catalysis (Dover, Mineola, New York, 2001), p. 57.

    Google Scholar 

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119334, Russia

    I. V. Kumpanenko, A. V. Roshchin, N. A. Ivanova, V. V. Novikov, A. M. Skryl’nikov, A. M. Podvalny & V. V. Usin

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  1. I. V. Kumpanenko
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  2. A. V. Roshchin
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  3. N. A. Ivanova
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  4. V. V. Novikov
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  5. A. M. Skryl’nikov
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  6. A. M. Podvalny
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  7. V. V. Usin
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Correspondence to I. V. Kumpanenko.

Additional information

Original Russian Text © I.V. Kumpanenko, A.V. Roshchin, N.A. Ivanova, V.V. Novikov, A.M. Skryl’nikov, A.M. Podvalny, V.V. Usin, 2017, published in Khimicheskaya Fizika, 2017, Vol. 36, No. 1, pp. 52–65.

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Kumpanenko, I.V., Roshchin, A.V., Ivanova, N.A. et al. Dynamic adsorption of nitrogen dioxide on zeolites. Russ. J. Phys. Chem. B 11, 154–166 (2017). https://doi.org/10.1134/S1990793117010055

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  • DOI: https://doi.org/10.1134/S1990793117010055

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