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The mechanism of action and the synergistic effect of nitrogenand phosphorus-containing fire retardants in fire protection and wood and peat fire suppression

Russian Journal of Physical Chemistry B volume 10, pages 306–312 (2016)Cite this article

Abstract

The factors exerting a significant influence on the termination of the combustion of natural materials (wood and peat) were studied with the use of synthetic nitrogen- and phosphorus-containing fire retardants with different efficiencies. With the use of a mathematical experimental design method, it was confirmed that the inhibition of gas-phase radical processes by volatile nitrogen-containing products is the predominant process of combustion suppression. It was found that the synergism of the nitrogen–phosphorus flame retardants is determined by their complex action: phosphorus mainly enters into organomineral structures in a the condensed phase, and nitrogen inhibits reactions in a gas phase.

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Authors and Affiliations

  1. Institute of Physicochemical Problems, Belarussian State University, Minsk, 220050, Belarus

    V. V. Bogdanova & O. I. Kobets

  2. Belarussian State University, Minsk, 220030, Belarus

    V. P. Kirlitsa

Authors
  1. V. V. Bogdanova
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  2. O. I. Kobets
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  3. V. P. Kirlitsa
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Correspondence to V. V. Bogdanova.

Additional information

Original Russian Text © V.V. Bogdanova, O.I. Kobets, V.P. Kirlitsa, 2016, published in Khimicheskaya Fizika, 2016, Vol. 35, No. 4, pp. 57–63.

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Bogdanova, V.V., Kobets, O.I. & Kirlitsa, V.P. The mechanism of action and the synergistic effect of nitrogenand phosphorus-containing fire retardants in fire protection and wood and peat fire suppression. Russ. J. Phys. Chem. B 10, 306–312 (2016). https://doi.org/10.1134/S1990793116020160

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  • DOI: https://doi.org/10.1134/S1990793116020160

Keywords

  • flame retardants
  • fire retardant efficiency
  • fire protection mechanism
  • natural combustible materials
  • wood
  • peat
  • mathematical design of experiments