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Consecutive reactions in a countercurrent plug-flow reactor. Gas-liquid system

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
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Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

A mathematical model of a bimolecular two-step consecutive exothermic reaction in the liquid phase of a gas-step consecutive exothermic reaction in the liquid phase of a gas-flow reactor is proposed. Spatial profiles of the heatings and relative concentrations of the reactants in both phases for the steady state of the system are presented. The behavior of the reaction intermediate product is examined. The kinetic characteristics of the reaction are demonstrated to substantially influence the behavior of the system in the reactor.

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References

  1. L. V. Kustova, Yu. N. Finaeva, N. G. Samoilenko, and B. L. Korsunskii, Khim. Fiz. 31 (7), 36 (2012).

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  2. D. A. Frank-Kamenetskii, Diffusion and Heat Transfer in Chemical Kinetics (Nauka, Moscow, 1987) [in Russian].

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Oblast, Russia

    L. V. Kustova, N. G. Samoilenko & B. L. Korsunskii

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    B. L. Korsunskii

Authors
  1. L. V. Kustova
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  2. N. G. Samoilenko
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  3. B. L. Korsunskii
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Corresponding author

Correspondence to B. L. Korsunskii.

Additional information

Original Russian Text © L.V. Kustova, N.G. Samoilenko, B.L. Korsunskii, 2013, published in Khimicheskaya Fizika, 2013, Vol. 32, No. 12, pp. 26–31.

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Kustova, L.V., Samoilenko, N.G. & Korsunskii, B.L. Consecutive reactions in a countercurrent plug-flow reactor. Gas-liquid system. Russ. J. Phys. Chem. B 7, 753–758 (2013). https://doi.org/10.1134/S1990793113060134

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  • DOI: https://doi.org/10.1134/S1990793113060134

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