Advertisement

Russian Journal of Physical Chemistry B

, Volume 6, Issue 4, pp 523–530 | Cite as

Promising energetic materials composed of nanosilicon and solid oxidizers

  • A. Yu. DolgoborodovEmail author
  • A. N. Streletskii
  • M. N. Makhov
  • V. A. Teselkin
  • Sh. L. Guseinov
  • P. A. Storozhenko
  • V. E. Fortov
Combustion, Explosion, and Shock Waves

Abstract

A method for production of mechanically activated energetic compositions consisting of nanosilicon and solid inorganic oxidizers is developed. For the compositions prepared, both high-speed burning and detonation are observed. The propagation of the reaction is accompanied by a high energy release, comparable to the heat of explosion of aluminized high explosives. The compositions are highly sensitive to thermal stimuli and capable of rapid deflagration-to-detonation transition. The results obtained in the work suggest that nanosilicon-based formulations as promising energetic materials for a wide range of applications, from initiating compositions in blasting caps to compositions for small charges in microsystem devices.

Keywords

high explosives nanosilicon perchlorates 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. Yu. Dolgoborodov, M. N. Makhov, I. V. Kolbanev, and A. N. Streletskii, RF Patent No. 2235085, Byull. Izobret., No. 24 (2004).Google Scholar
  2. 2.
    A. Yu. Dolgoborodov, A. N. Streletskii, M. N. Makhov, I. V. Kolbanev, and V. E. Fortov, Russ. J. Phys. Chem. B 1, 606 (2007).CrossRefGoogle Scholar
  3. 3.
    A. Yu. Dolgoborodov, A. N. Streletskii, I. V. Kolbanev, and M. N. Makhov, in Proceedings of the 35th International Pyrotechnics Seminar, Fort Collins, Colorado, 2008, Ed. by F. J. Schelling (IPSUSA Seminars, Denver, 2008), p. 169.Google Scholar
  4. 4.
    P. A. Storozhenko, Sh. L. Guseinov, and S. I. Malashin, Nanotechnol. Russia 4, 62 (2009).CrossRefGoogle Scholar
  5. 5.
    A. F. Belyaev, V. K. Bobolev, A. I. Korotkov, A. A. Sulimov, S. V. Chuiko, Transition of Combustion of Condensed System to Explosion (Nauka, Moscow, 1973) [in Russian].Google Scholar
  6. 6.
    V. A. Teselkin, A. N. Streletskii, A. N. Kolbanev, and A. Yu. Dolgoborodov, Combustion and Explosion, Ed. by S. M. Frolov (Torus, Moscow, 2009), No. 2, p. 141 [in Russian].Google Scholar
  7. 7.
    V. A. Teselkin, A. N. Streletskii, A. N. Kolbanev, and A. Yu. Dolgoborodov, Combustion and Explosion, Ed. by S. M. Frolov (Torus, Moscow, 2010), No. 3, p. 292 [in Russian].Google Scholar
  8. 8.
    Recommendations on the Transport of Dangerous Goods. Manual of Tests and Criteria, 4th ed. (United Nations, New York, 2003). ST/SG/AC.10/11/Rev.4Google Scholar
  9. 9.
    B. P. Berger, B. Haas, P. Folly, J. Mathieu, T. Vine, and T. T. Griffiths, in Proceedings of the 33rd International Pyrotechnics Seminar, Fort Collins, Colorado, 2006 (IPSUSA Seminars, Denver, 2006), p. 81.Google Scholar
  10. 10.
    M. N. Makhov, Khim. Fiz. 19(6), 52 (2000).Google Scholar
  11. 11.
    M. N. Makhov, Khim. Fiz. 19(9), 83 (2000).Google Scholar
  12. 12.
    M. N. Makhov, in Proceedings of International Conference 7th Kharitonov Topical Scientific Readings, Sarov, Russia, 2005 (Ross. Fed. Yad. Tsentr-Vseross. Nauchn.-Issl. Inst. Eksp. Fiz., Sarov, 2005), p. 53.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  • A. Yu. Dolgoborodov
    • 1
    Email author
  • A. N. Streletskii
    • 1
  • M. N. Makhov
    • 1
  • V. A. Teselkin
    • 1
  • Sh. L. Guseinov
    • 2
  • P. A. Storozhenko
    • 2
  • V. E. Fortov
    • 3
  1. 1.Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia
  2. 2.State Research Institute of Chemistry and Technology of Organoelement CompoundsMoscowRussia
  3. 3.Joint Institute of High TemperaturesRussian Academy of SciencesMoscowRussia

Personalised recommendations