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Russian Journal of Physical Chemistry B

, Volume 6, Issue 3, pp 341–347 | Cite as

Chirooptical effects in dilute solutions of gelators

  • S. V. StovbunEmail author
  • A. M. Zanin
  • D. S. Skorobogat’ko
  • A. A. Skoblin
  • Ya. A. Litvin
  • A. I. Mikhailov
  • O. N. Krutius
  • R. G. Kostyanovskii
Structure of Chemical Compounds. Spectroscopy

Abstract

The chirooptical properties of a number of compounds in a variety of achiral solvents are studied. The results are interpreted within the framework of the standard model of chiral molecules. It is demonstrated that, with increasing concentration, chiral aggregates emerge, up to the formation of a macrophase (strings), which radically changes the chirooptical characteristics of the solution.

Keywords

circular dichroism mesophase chiral associates chirooptical properties 

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References

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    S. V. Stovbun, O. M. Krutius, A. M. Zanin, D. S. Skorobogat’ko, and R. G. Kostyanovskii, Russ. J. Phys. Chem. B 5, 846 (2011).CrossRefGoogle Scholar
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Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  • S. V. Stovbun
    • 1
    Email author
  • A. M. Zanin
    • 1
  • D. S. Skorobogat’ko
    • 1
  • A. A. Skoblin
    • 1
  • Ya. A. Litvin
    • 1
  • A. I. Mikhailov
    • 1
  • O. N. Krutius
    • 1
  • R. G. Kostyanovskii
    • 1
  1. 1.Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia

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