Russian Journal of Physical Chemistry B

, Volume 6, Issue 4, pp 543–552 | Cite as

Microphase separation in a melt of graft copolymers formed by blocks with different grafting densities

  • N. Yu. Kuz’minykh
  • M. A. AlievEmail author
Chemical Physics of Polymer Materials


The weak-segregation phase behavior of a monodisperse melt of a binary graft copolymer the macromolecules of which consist of two blocks with different densities of grafting of side chains is investigated. The length of the side chains in each block is assumed to be the same. Analysis of the structure factor of the system indicates the possibility of formation of two-scale structures in the melt. The realized scales differ significantly from each other and correspond to a phase separation between the blocks and between the monomeric units that form the repeating fragment of the graft copolymer. Classification diagrams are constructed, which describe the scale of the structures formed in the melt at different values of the parameters of the chemical structure of the macromolecules.


microphase separation copolymers 


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© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  1. 1.Emanuel Institute of Biochemical PhysicsRussian Academy of SciencesMoscowRussia

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