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Phase diagram of BaCl2-NaCl-H2O at temperatures up to 530°C and pressures up to 150 MPa

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Abstract

Experimental studies of high-temperature phase equilibria in the BaCl2-NaCl-H2O made it possible to determine the conditions of heterogenization of homogeneous supercritical (SC) fluids spreading from the BaCl2-H2O binary subsystem of type 2 and to reveal the continuity of the transformation of gasliquid equilibria into equilibria of phase separation in SC environment. Comparison with the characteristics of the K2SO4-KCl-H2O system suggests that ternary systems with one volatile component formed by binary subsystems of type 2 with phase separation and of type 1 without separation have the same type of phase diagrams.

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References

  1. V. M. Valyashko, Pure Appl. Chem. 74, 1871 (2002).

    Article  CAS  Google Scholar 

  2. V. M. Valyashko, M. A. Urusova, and K. G. Kravchuk, Dokl. Akad. Nauk SSSR 272, 390 (1983).

    CAS  Google Scholar 

  3. M. I. Ravich, Water-Salt Systems at Elevated Temperatures and Pressures (Nauka, Moscow, 1974) [in Russian].

    Google Scholar 

  4. V. M. Valyashko, Phase Equilibria and Properties of Hydrothermal Systems (Nauka, Moscow, 1990) [in Russian].

    Google Scholar 

  5. V. M. Valyashko, in Hydrothermal Properties of Materials, Pt. 1, Ed. by V. M. Valyashko (Wiley, UK, 2008), p. 1.

    Google Scholar 

  6. N. K. Voskresenskaya et al., Handbook on Fusibility of Salt Systems (Akad. Nauk SSSR, Moscow, 1961), Vol. 1 [in Russian].

    Google Scholar 

  7. W. C. Schroeder, A. Gabriel, and E. P. J. Partrige, Am. Chem. Soc. 57, 1539 (1935).

    Article  CAS  Google Scholar 

  8. Kh. Ataev et al., Zh. Neorg. Khim. 39, 523 (1994).

    CAS  Google Scholar 

  9. M. A. Urusova, V. M. Valyashko, and I. M. Grigor’ev, Russ. J. Inorg. Chem. 52, 405 (2007).

    Article  Google Scholar 

  10. M. A. Urusova and V. M. Valyashko, Russ. J. Inorg. Chem. 50, 1754 (2005).

    Google Scholar 

  11. M. A. Urusova and V. M. Valyashko, Russ. J. Inorg. Chem. 53, 604 (2008).

    Article  Google Scholar 

  12. M. A. Urusova and V. M. Valyashko, Russ. J. Inorg. Chem. 54, 759 (2009).

    Article  Google Scholar 

  13. M. A. Urusova and V. M. Valyashko, Russ. J. Inorg. Chem. 56, 430 (2011).

    Article  CAS  Google Scholar 

  14. I. R. Krichevskii, Phase Equilibria in Solutions at High Pressures (Goskhimizdat, Moscow, 1957) [in Russian].

    Google Scholar 

  15. D. S. Tsiklis, Stratification of Gaseous Mixtures (Khimiya, Moscow, 1969) [in Russian].

    Google Scholar 

  16. I. D. van der Waals and F. Constamm, Lehrbuch der Thermostatik (Johann Ambrosius Barth, Leipzig, 1927; ONTI, Moscow, 1936), Part 2.

    Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. A. Urusova, S. V. Makaev, E. V. Maleeva, N. S. Ivanova & V. M. Valyashko

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  1. M. A. Urusova
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  2. S. V. Makaev
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  3. E. V. Maleeva
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  4. N. S. Ivanova
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  5. V. M. Valyashko
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Correspondence to V. M. Valyashko.

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Original Russian Text © M.A. Urusova, S.V. Makaev, E.V. Maleeva, N.S. Ivanova, V.M. Valyashko, 2011, published in Sverkhkriticheskie Flyuidy: Teoriya i Praktika, 2011, Vol. 6, No. 2, pp. 922-113.

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Urusova, M.A., Makaev, S.V., Maleeva, E.V. et al. Phase diagram of BaCl2-NaCl-H2O at temperatures up to 530°C and pressures up to 150 MPa. Russ. J. Phys. Chem. B 5, 1173–1188 (2011). https://doi.org/10.1134/S1990793111070165

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  • DOI: https://doi.org/10.1134/S1990793111070165

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