Skip to main content
SpringerLink
Log in

An analysis of absorption-desorption of volatile organic compounds by molecularly imprinted polymer films

  • Chemical Physics of Polymer Materials
  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

A theoretical analysis of the experimental data on absorption (desorption) of volatile organic compounds by (from) molecularly imprinted polymer films was performed. The theoretical time dependences of the amount of absorbed analyte in a film were calculated using a system of equations with four kinetic parameters (Γ, K, K sur , and C eq ), which were determined by theoretically approximating the experimental data. The special features of the absorption-desorption process in a polymer film were suggested to be described using a parameter called the specificity coefficient. Specificity coefficients were determined for all the polymers and analytes studied. The specificity coefficients obtained from the chromatographing data were compared with the imprinting factors of chromatograms calculated from the experimental retention time values. An empirical linear dependence of specificity coefficients on imprinting factor values was obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. V. Losev, A. V. Medved’, A. V. Roshchin, et al., Khim. Fiz. 28(11), 84 (2009) [Russ. J. Phys. Chem. B 3, 990 (2009)].

    Google Scholar 

  2. V. V. Losev, A. V. Roshchin, I. D. Epinat’ev, et al., Vysokomol. Soedin., Ser. A 52(2), 1 (2010) [Polymer Sci., Ser. A 52, 308 (2010)].

    Google Scholar 

  3. Y. Fu, PhD Dissertation (Morgantown, 2003).

  4. J. Courtois, G. Fischer, B. Sellergren, and K. Irgum, J. Chromatography A 1109, 92 (2006).

    Article  CAS  Google Scholar 

  5. I. R. Dunkin, J. Lenfeld, and D. C. Sherrington, Polymer 34, 77 (1993).

    Article  CAS  Google Scholar 

  6. S. Z. Roginskii, M. I. Yanovskii, and A. D. Berman, Principles of Applying Chromatography in Catalysis (Nauka, Moscow, 1972) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, Russia

    A. V. Bloshenko, A. V. Roshchin, I. V. Kumpanenko & N. A. Ivanova

Authors
  1. A. V. Bloshenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Roshchin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Kumpanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. A. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. V. Kumpanenko.

Additional information

Original Russian Text © A.V. Bloshenko, A.V. Roshchin, I.V. Kumpanenko, N.A. Ivanova, 2011, published in Khimicheskaya Fizika, 2011, Vol. 30, No. 3, pp. 84–96.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bloshenko, A.V., Roshchin, A.V., Kumpanenko, I.V. et al. An analysis of absorption-desorption of volatile organic compounds by molecularly imprinted polymer films. Russ. J. Phys. Chem. B 5, 332–344 (2011). https://doi.org/10.1134/S1990793111020187

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793111020187

Keywords

Search

Navigation