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The influence of the drift shift of electrons undergoing thermalization on the kinetic characteristics of geminate conductivity and recombination

  • Electrical and Magnetic Properties of Materials
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Abstract

A program for numerically solving the Smoluchowski equation with a modified initial condition taking into account the drift shift of electrons that experience thermalization in an external electric field was developed. The probability of survival and the polarization current of isolated ion pairs were calculated. Shift effects were shown to be especially strong in the region of medium electric fields on the order of 107 V/m and noticeably weaker in both low and high fields. This was related to the proportional relation between the drift shift and electric field applied. The program was used to critically analyze the available experimental data on pulsed photoconductivity of polyacenes.

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Authors and Affiliations

  1. Research Institute of Instruments, Lytkarino, Moscow oblast, Russia

    R. Sh. Ikhsanov

  2. Moscow State Institute of Electronics and Mathematics, Technical University, Moscow, Russia

    A. P. Tyutnev, V. S. Saenko & E. D. Pozhidaev

Authors
  1. R. Sh. Ikhsanov
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  2. A. P. Tyutnev
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  3. V. S. Saenko
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  4. E. D. Pozhidaev
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Corresponding author

Correspondence to A. P. Tyutnev.

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Original Russian Text © R.Sh. Ikhsanov, A.P. Tyutnev, V.S. Saenko, E.D. Pozhidaev, 2008, published in Khimicheskaya Fizika, 2008, Vol. 27, No. 10, pp. 84–89.

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Ikhsanov, R.S., Tyutnev, A.P., Saenko, V.S. et al. The influence of the drift shift of electrons undergoing thermalization on the kinetic characteristics of geminate conductivity and recombination. Russ. J. Phys. Chem. B 2, 740–744 (2008). https://doi.org/10.1134/S199079310805014X

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  • DOI: https://doi.org/10.1134/S199079310805014X

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