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Steady regimes of exothermic autocatalytic reaction in a continued stirred-tank reactor

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Abstract

A continued stirred-tank reactor with an exothermic autocatalytic reaction running in it is modeled. In contrast to the simple kinetic law formulated in terms of a first-order equation, a variety of possible types of thermal isoclines, including isoles, are found for the autocatalytic process in the dimensionless “degree of conversion-temperature” coordinates. A bifurcation curve separating the domains of existence of one and three steady states is constructed in the Se-Da coordinates.

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Authors and Affiliations

  1. Institute of New Chemical Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    B. L. Korsunskii, N. G. Samoilenko & E. V. Deyun

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 117977, Russia

    B. L. Korsunskii

  3. Moscow Engineering Physics Institute (Technical University), Kashirskoe sh. 31, Moscow, 115409, Russia

    A. O. Il’chenko

Authors
  1. B. L. Korsunskii
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  2. N. G. Samoilenko
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  3. E. V. Deyun
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  4. A. O. Il’chenko
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Additional information

Original Russian Text © B.L. Korsunskii, N.G. Samoilenko, E.V. Deyun, A.O. Il’chenko, 2008, published in Khimicheskaya Fizika, 2008, Vol. 27, No. 6, pp. 14–19.

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Korsunskii, B.L., Samoilenko, N.G., Deyun, E.V. et al. Steady regimes of exothermic autocatalytic reaction in a continued stirred-tank reactor. Russ. J. Phys. Chem. B 2, 426–430 (2008). https://doi.org/10.1134/S1990793108030159

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  • DOI: https://doi.org/10.1134/S1990793108030159

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