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Rare-Earth Elements and Noble Metals in Phosphorites of the Gremuchy Occurrence, Lesser Khingan, Far East of Russia

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Abstract

Numerous phosphorite occurrences are located among the Riphean–Early Cambrian rocks of the Khingan Group (Lessr Khingan, JAO). They are associated spatially and genetically with uranium, iron, and manganese ore occurrences. The phosphorites of the Gremuchy occurrence are enriched in rare-earth elements (REE) and yttrium (up to 813.58 g/t), uranium (up to 52.23 g/t), and gold (up to 17.03 g/t), and can be considered as a complex of phosphorus–uranium–gold–rare-earth ores. REE-rich fluorapatite is the main concentrator of phosphorus in these rocks. REE do not form their own minerals, while gold, silver, and platinum are found as microinclusions. The concentrations of phosphorus, radioactive, and rare-earth elements are positively correlated with the organic carbon content, which supports their coprecipitation from seawater enriched in rare and rare-earth elements supplied by hydrothermal vents on the surface of the slope of seamount volcanoes.

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REFERENCES

  1. N. V. Berdnikov, V. G. Nevstruev, and B. G. Saksin, “Sources and formation conditions of ferromanganese mineralization of the Bureya and Khanka massifs, Russian Far East,” Russ. J. Pac. Geol. 10 (4), 263–273 (2016).

    Article  Google Scholar 

  2. V. V. Bliskovskii, Composition and Dressibility of Phosphorite Ores (Nedra, Moscow, 1983) [in Russian].

    Google Scholar 

  3. M. I. Voskresenskaya, “On genesis of the Pad’ Tigrovaya uranium–phosphate deposits at Lesser Khinga,” in Problems of Genesis of the Uranium Deposits in the Precambrian and Early Paleozoic Sedimentary and Volcanosedimentary Complexes (VSEGEI, Leningrad, 1971), pp. 148–164 [in Russian].

    Google Scholar 

  4. Guyots of Western Pacific and their Ore Potential, Ed, by Yu. G. Volokhin, M. E. Mel’nikov, E. L. Shkol’nik, et al., (Nauka, Moscow, 1995) [in Russian].

  5. A. V. Kazakov, “Fluorapatite equilibrium system under conditions of formation of sedimentary rocks,” Tr. IGN AN SSSR, No. 114 (1950).

  6. A. V. Kazakov and E. I. Sokolova, “Conditions of fluorite formation in sedimentary rocks (fluorite system),” Tr. IGN AN SSSR, No. 114 (1950).

  7. V. A. Nagornyi, “Composition and sedimentation transformations of ancient phosphate Kingan–Bureya massif,” in Petrology of the Amur Region (DVNTs AN SSSR, Vladivostok, 1981), pp. 113–120 [in Russian].

  8. V. A. Nagornyi and G. V. Roganov, “New data on carbonate phosphorites and phosphate–carbonate rocks in the Amur region,” in Phosphate-Bearing Formations of the Far East (DVNTs AN SSSR, Vladivostok, 1984), pp. 74–89 [in Russian].

  9. S. M. Rodionov and G. V. Roganov, “Mineral phosphate raw material of the Far East and problems of its development,” Tikhookean. Geol. 25 (1), 81–89 (2006).

    Google Scholar 

  10. A. I. Khanchuk, N. V. Berdnikov, A. A. Cherepanov, and N. S. Konovalova, “Finely dispersed gold and PGEM in the graphitse shales of the Bureya massif as a new type of noble metal mineralization at the Russian Far East,” Gorn. Inform.-Analit. Byull., No. 5, pp. 9–18.

  11. A. I. Khanchuk, V. G. Nevstruev, N. V. Berdnikov, and V. P. Nechaev, “Petrochemical characteristics of Carbonaceous shales in the Eastern Bureya massif and their precious-metal mineralization,” Russ. Geol. Geophys., 54 (6), 815–828 (2013).

    Article  Google Scholar 

  12. A. A. Cherepanov, N. V. Berdnikov, A. V. Shtareva, and V. O. Krutikova, “Formation conditions and rare-earth mineralization of Riphean Carbonaceous shales of the Upper Nyatygran subformation, Russian Far East,” Russ. J. Pac. Geol. 11 (4), 297–307 (2017).

    Article  Google Scholar 

  13. A. A. Cherepanov and V. V. Gostishchev, “Carbonaceous shales of the Bureya massif as possible source of rare-earth metals,” Rudy Met., No. 3, 68–76 (2017).

  14. M. Bau, “Controls on the Fractionation of Isovalent Trace Elements in Magmatic and Aqueous Systems: Evidence from Y/Ho, Zr/Hf, and Lanthanide Tetrad Effect,” Contrib. Mineral. Petrol. 123, 323–333 (1996).

    Article  Google Scholar 

  15. L. P. Gromet, R. F. Dymeck, L. A. Haskin, et al., “The “North American Shale Composite”: Its Compilation, Major and Trace Element Characteristics,” Geochim. Cosmochim. Acta 48, 2469–2482 (1984).

    Article  Google Scholar 

  16. L. A. Haskin, M. A. Haskin, F. A. Frey, and T. R. Wildman, “Relative and absolute terrestrial abundances of the rare earth,” Origin and Distribution of the Elements, Oxford: Pergamon, 1968, Vol. 1, pp. 889–991.

    Google Scholar 

  17. K. Nicholson, “Stratiform manganese mineralization near inverness, Scotland: a Devonian sublacustrine hot-spring deposit?,” Miner. Deposita 25, 126–131 (1990).

    Article  Google Scholar 

  18. T. Plank and C. H. Langmuir, “The chemical composition of subducting sediment and Its consequences for the crust and mantle,” Chem. Geol. 145 (3–4), 325–394 (1998).

    Article  Google Scholar 

  19. J. R. Toth, “Deposition of submarine crusts rich in manganese and iron,” Geol. Soc. Am. Bull. Part V, 44–54 (1980).

  20. J. Zhang and Y. Nozaki, “Rare earth elements and yttrium in seawater: ICP-MS determinations in the East Caroline, Coral Sea, and South Fiji Basins of the western south Pacific Ocean,” Geochim. Cosmochim. Acta 60, 4631–4644 (1996).

    Article  Google Scholar 

  21. J. Zhang and Y. Nozaki, “Behavior of rare earth elements in seawater at the ocean margin: a study along the slopes of the Sagami and Nankai troughs near Japan,” Geochim. Cosmochim. Acta 62, 1307–1317 (1998).

    Article  Google Scholar 

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Funding

The studies were carried out in the framework of the State Task of the Kosygin Institute of Tectonics and Geophysics of the Far East Branch of the Russian Academy of Sciences.

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Correspondence to N. V. Berdnikov.

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Recommended for publishing by A.I. Khanchuk

Translated by M. Bogina

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Cherepanov, A.A., Berdnikov, N.V. & Shtareva, A.V. Rare-Earth Elements and Noble Metals in Phosphorites of the Gremuchy Occurrence, Lesser Khingan, Far East of Russia. Russ. J. of Pac. Geol. 13, 585–593 (2019). https://doi.org/10.1134/S1819714019060022

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