The by-products of the Far East Sn deposits related to Li–F granites include trace elements. The petrography and mineral composition of the Sn-bearing metasomatites of the Verkhneurmiysky ore cluster (VUOC) of the Amur region (feldspatites, greisens, zwitters, turmalinites, and chloritites) and the multistage complex rare-metal (RM) mineralization of the Sn occurrences in area of Li–F granites are studied. The minerals of strategic metals (Nb, Ta, W, Y, REE (from La to Lu), Be, Li, Rb, Zr, Hf, In, Sc, Se, Cd, and Te) are found. The RMs occur as minerals (fergusonite, plumbopyrochlore, allanite, monazite, roquesite, sakuraiite, etc.) and isomorphic substitution in the ore (wolframite; cassiterrite; Cu, Sn, Fe, Mo, Zn, and Pb sulfides; native bismuth; etc.) and rock-forming (fluorite, siderophyllite, muscovite, and epidote) minerals. Some RMs (Y, REEs, Nb, In, and Sc) most frequently occur in Sn-bearing metasomatites. The RM minerals formed during the VUOC evolution (from the premineral feldspatite to the postmineral chloritite stage) with decreasing intensity of RM mineral formation and compositional evolution from lithophile to chalcophile RMs: (LREE, Zr, Hf) → (W, Nb, Ta, Y, HREEs, Sc) → (Sn, In, Cd, Se, Te). The formation of the VUOC RM mineralization was caused by magmatic, metasomatic, and crystal chemical factors. The possible complex exploration of the Far East Sn deposits is shown for areas of Li–F granites.
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V. I. Alekseev, “Metsomatuc zoning of the ore fields of the Badzhal district (Amur region),” Zap. Vses. Mineral. O-va, No. 5, 27–37 (1989).
V. I. Alekseev, Lithium–Fluorine Granites of the Far East (Natsional’nyi mineral’no-syr’evoi universitet “Gornyi”, St. Petersburg, 2014) [in Russian].
V. I. Alekseev and Yu. B. Marin, “Composition and evolution of accessory mineralization of the lithium–fluorine granites of the Far East as indicator of their ore,” Zap. Ross. Mineral. O-va, No. 6, 1–16 (2014).
V. I. Alekseev, K. G. Sukhanova, and Yu. B. Marin, “Niobium minerals as indicators of genetic relation of the tin zwitter and lithium–fluorine granites of the Upper Amur massif, Amur region,” Zap. Ross. Mineral. O-va, No. 1, 55–100 (2018).
S. M. Beskin, V. N. Larin, and Yu. B. Marin, Rare-Metal Granite Formations (Nedra, Leningrad, 1979) [in Russian].
S. M. Beskin and Yu. B. Marin, “Complex systematic of the tantalum and tantalum–niobium deposits,” Zap. Ross. Mineral. O-va, No. 3, 45–54 (2015).
N. S. Bortnikov, A. V. Volkov, A. L. Galyamov, et al., “Mineral resources of high-tech metals in Russia: state of the art and outlook,” Geol. Ore Deposits 58 (2), 83–104 (2016).
R. L. Brodskaya and Yu. B. Marin, “Ontogenetic analysis on micro and nano-level of mineral individuals and aggregates for reconstruction of ore-formation conditions and assessment of technological properties of raw material,” J. of Mining Institute . 219, 369–376 (2016).
L. Z. Bykhovskii and S. D. Potanin, “Geological-economic types of rare-metal depositrs,” in Mineral Raw Material. Geological-Economic Series, (VIMS, Moscow, 2009), vol. 28 [in Russian].
V. V. Gavrilenko and E. G. Panova, Geochemistry, Genesis, and Typomorphism of Minerals of the Tin and Tungsten Deposits, (Nevskii kur’er, St. Petersburg, 2001) [in Russian].
I. V. Gaskov, A. G. Vladimirov, A. I. Khanchuk, G. A. Pavlova, and V. I. Gvozdev, “Distribution of indium in ores of some base metal and tin–sulfide deposits in Siberia and the Russian Far East,” Geol. Ore Deposits 59 (1), 56–67 (2017).
Geodinamika, magmatizm i metallogeniya Vostoka Rossii,, Ed. by A.I. Khanchuka (Dal’nauka, Vladivostok, 2006) [in Russian].
V. G. Gonevchuk, Tin-Bearing Magmatic Systems of the Far East: Magmatism and Ore Genesis (Dal’nauka, Vladivostok, 2002) [in Russian].
State Geological Map of the Russian Federation. 1 : 1 000 000 (Third Generation). Far East Series. Sheet M-53—Khabarovsk: Explanatory Note (Kartfabrika VSEGEI, St. Petersburg, 2009) [in Russian].
State Geological Map of the Russian Federation. 1 : 200 000. 2nd Ed. Komsomol’skaya Series. Sheet M-53-XV (Yarap R.): Explanatory Note (Kartfabrika VSEGEI, St. Petersburg, 2004), p. 159 [in Russian].
A. A. Kremenetskii and E. A. Kalish, “Compelx rare-metal deposits of Russia and main directions of increase of their investment attraction,” Razved. Okhr. Nedr, No. 9, 3–11 (2014).
V. G. Kryukov and L. I. Shcherbak, “Geology and metallogeny of the Badzhal tin district,” Sov. Geologiya, No. 3, 55–65 (1987).
Yu. B. Marin, G. T. Skublov, and Yu. L. Gul’bin, “Mineral–geochemical criteria for local prediction of rare-metal deposits,” in Mineralogical Mapping and Indicator Mineralization (Nauka, Leningrad, 1990), pp. 67–94 [in Russian].
V. I. Popova, V. A. Popov, P. G. Korostelev, and V. V. Orlovskii, Mineralogy of the Ores of the W–Sn Tigrinoe deposit at Sikhote Alin and prospects of its development (RMO UrO RAN, Yekaterinburg, 2013) [in Russian].
A. K. Rub and M. G. Rub, Rare-Metal Granites of the Amur Region (VIMS, Moscow, 2006) [in Russian].
B. I. Semenyak, “On "zwitters” of the Upper Amur ore cluster," in Far East Ore Deposits (DVNTs AN SSSR, Vladivostok, 1983), pp. 20–25 [in Russian].
B. I. Semenyak, A. P. Nedashkovskii, and N. N. Ni-kulin, “Indium minerals in the ores of the Pravourmiisky Deposit (Russian Far East),” Geol. Rudn. Mestorozhd. 13 (3), 230–236 (1994).
V. V. Smolenskii, V. V. Gavrilenko, U. Kempe, and D. Vol’f, “Rare-metal elements in the minerals of the Far East tin deposits,” Zap. Vseross. Mineral. O-va, No. 4, 101–109 (1998).
N. A. Solodov, Metallogeny of Rare-Metal Formations (Nedra, Moscow, 1985) [in Russian].
V. A. Trunilina, Yu. S. Orlov, A. I. Zaitsev, and S. P. Roev, “High-phosphorous lithium–fluorine granites of Eastern Yakutia (Verkhoyansk–Kolyma orogenic region),” Russ. J. Pac. Geol. 13 (1), 82–98 (2019).
B. L. Flerov, V. A. Trunilina, A. I. Kholmogorov, and Ya. V. Yakovlev, “Geological–genetic model of the formation of tin deposits of Yakutia,” in Ore Formation and Genetic Models of the Endogenous Ore Formations (Nauka, Novosibirsk, 1988), pp. 262–271 [in Russian].
A. I. Khanchuk, “Paleogeodynamic analysis of the formation of ore deposits of the Russian Far East,” in Ore Deposits of Continental Margins (Dal’nauka, Vladivostok, 2000), pp. 5–34 [in Russian].
A. I. Khanchuk, N. V. Gorelikova, V. Pavlovska-Glen, and R. Tolozana-Del’gado, “New data on trace element distribution in cassiterite from tin deposits of the Russian Far East,” Dokl. Earth Sci. 399 (1), 1146–1149 (2004).
A. A. Shnaider and G. V. Ruchkin, “Assesment of prospects of ore potential of the Stlanikov ore manifestation in Primorye,” Tikhookean. Geol. 36 (6), 111–121 (2017).
P. Cerny, P. L. Blevin, M. Cuney, and D. London, “Granite-related ore deposits,” Econ. Geol., 100 (2005).
H. Legros, C. Marignac, T. Tabary, J. Mercadier, A. Richchard, M. Cuney, R. C. Wang, N. Charles, and M.-Y. Lespinasse, “The ore-forming magmatic-hydrothermal system of the Piaotang W–Sn Deposit (Jiangxi, China) as seen from Li-mica geochemistry,” Am. Mineral. 103 (1), 39–54 (2018).
M. W. Verplanck, M.W. Hitzman, “Rare earth and critical elements in ore deposit,” Rev. Econ. Geol. 18, 365 (2016).
R. C. Wang, L. Xie, J. J. Lu, J. C. Zhu, J. Chen, “Diversity of Mesozoic tin-bearing granites in the Nanling and adjacent regions, South China: distinctive mineralogical patterns,” Sci. China Earth Sci 60 (11), 1909–1919 (2017).
L. Xie, Z. J. Wang, R. C. Wang, J. C. Zhu, X. D. Che, J. F. Gao, X. Zhao, “Mineralogical constraints on the genesis of W–Nb–Ta mineralization in the Laiziling Granite (Xianghualing District, South China),” Ore Geol. Rev. 95, 695–712 (2018).
This work was supported by the Ministry of Science and Education of the Russian Federation (State Contract no. 5.9248.2017/6.7 for 2017–2019).
Recommended for publishing by A.I. Khanchuk
Translated by I. Melekestseva
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Alekseev, V.I., Marin, Y.B. & Gavrilenko, V.V. Rare-Metal Mineralization of Sn Occurrences in the Area of Li–F Granites, Verkhneurmiysky Ore Cluster, Amur Region. Russ. J. of Pac. Geol. 13, 120–131 (2019). https://doi.org/10.1134/S1819714019020027
- rare metals
- Li–F granites
- Verkhneurmiysky ore cluster
- Amur region