Skip to main content
Log in

REE geochemistry in groundwater of the Sikhote Alin fold region (Russian Far East)

  • Published:
Russian Journal of Pacific Geology Aims and scope Submit manuscript

Abstract

Analysis of the distribution and fractionation of rare earth elements in the groundwater of the Sikhote Alin fold region reveals that their concentrations, geochemistry, and fractionation ability vary in different groundwater types depending on many factors, including the pH–Eh parameters and mineralization of the solutions and the composition of the host rocks. The results of monitoring of changes in the REE concentrations in the groundwater of the region over ten years provides the opportunity to establish the range of their variations. Inorganic forms of REE migration are rated for all geochemical types of water in the meteoric–surface–ground water system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. A. Vakh and N. A. Kharitonova, “Rare-earth element geochemistry and distribution in the groundwaters of the Fadeev Mineral Water Deposit,” Regional. Geol. Metallogen., No. 43, 106–113 (2010).

    Google Scholar 

  2. E. A. Vakh and N. A. Kharitonova, “Rare-earth element geochemistry and distribution in the groundwaters and host rocks of the Niznie Luzhki mineral water deposit,” Inzhener. Geol., No. 4, 60–67 (2010).

    Google Scholar 

  3. E. A. Vakh, N. A. Kharitonova, and A. S. Vakh, “Behavior of rare-earth element durin formation of carbonated–hydrocarbonated mineral waters of Primorye,” Izv. Vyssh. Uchebn. Zaved., Geol. Razved., No. 4, 48–58 (2013).

    Google Scholar 

  4. S. R. Teilor and S. M. McLennan, The Continental Crust: Its Composition and Evolution (Blackwell Scientific Publications, Oxford, 1985).

    Google Scholar 

  5. N. A. Kharitonova, G. A. Chelnokov, V. V. Kulakov, and N. N. Zykin, “Geochemistry of the mineral waters and gases of the Mukhen Deposit, Far East,” Russ. J. Pac. Geol. 2 6, 535–544 (2008).

    Article  Google Scholar 

  6. N. A. Kharitonova, G. A. Chelnokov, E. A. Vakh, A. A. Karabtsov, and N. N. Zykin, “Geochemistry of carbonated mineral waters from the Fadeevskoe Deposit of the Primorye Region,” Russ. J. Pac. Geol. 4 1, 78–90 (2010).

    Article  Google Scholar 

  7. N. A. Kharitonova, G. A. Chelnokov, E. A. Vakh, and V. A. Goryachev, “Geochemistry of carbonated mineral waters of the Nizhnie Luzhki Deposit, Primorye,” Tikhookean. Geol. 30 1, 108–118 (2011).

    Google Scholar 

  8. N. A. Kharitonova and G. A. Chelnokov, “Formation of carbonated mineral waters of the Gornovodnoe Deposit, Primorye, Russia,” Geoekol., Inzh. Geol., Gidrogeol., Geokriol., No. 6, 486–502 (2011).

    Google Scholar 

  9. N. A. Kharitonova, G. A. Chelnokov, I. V. Bragin, and E. A. Vakh, “Isotope composition of natural waters of the southern Russian Far East,” Tikhookean. Geol., No. 2, 75–87 (2012).

    Google Scholar 

  10. N. A. Kharitonova, Extended Abstract of Doctoral Dissertation in Geology and Mineralogy (Tomsk, 2013).

    Google Scholar 

  11. G. A. Chelnokov and N. A. Kharitonova, Carbonated Mineral Waters of Southern Russian Far East, Ed. by V. V. Kulakov (Dal’nauka, Vladivostok, 2008) [in Russian].

  12. G. A. Chelnokov, N. A. Kharitonova, and M. K. Vasil’eva, “Geochemistry and genesis of underground brines in northeastern Ussuri Bay, Primorye,” Geoekol. Inzh. Geol. Gidrogeol. Geokriol., No. 4, 310–319 (2012).

    Google Scholar 

  13. O. V. Chudaev, Composition and Genesis of Hydrothermal Systems of Russian Far East (Dal’nauka, Vladivostok, 2003) [in Russian].

    Google Scholar 

  14. V. A. Chudaeva and O. V. Chudaev, “Accumulation and fractionation of rare earth elements in surface waters of the Russian Far East under the conditions of natural and anthropogenic anomalies,” Geochem. Int. 49 5, 498–524 (2011).

    Article  Google Scholar 

  15. K. V. Chudnenko and I. K. Karpov, “Selektor–Windows. A software for Calculation of Chemical Equilibria by Minimization of Thermodynamic Potentials. A Brief Guide (Irkutsk, 2003) [in Russian].

    Google Scholar 

  16. M. Bau, “Scavenging of dissolved yttrium and rare earths by precipitating iron oxyhydroxides: experimental evidence for Ce oxidation, Y-Ho fractionation, and lanthanide tetrad effect,” Geochim. Cosmochim. Acta, 67–77 (1999).

    Google Scholar 

  17. R. Biddau, R. Cidu, and F. Frau, “Rare earth elements in waters from albitite bearing granodiorites of Central Sardinia, Italy,” Chem. Geol. 182, 1–14 (2002).

    Article  Google Scholar 

  18. R. N. Byrne and K. N. Kim, “Rare earth elements scavenging in seawater,” Geochim. Cosmochim. Acta 54, 2645–2656 (1990).

    Article  Google Scholar 

  19. R. H. Byrne and E. R. Sholkovitz, “Marine chemistry and geochemistry of the lanthanides,” in Handbook on the Physics and Chemistry of Rare Earths? Ed. by A. Gschneidner. and L. R. Eyring (Elsevier, Amsterdam, 1996), Vol. 23, pp. 497–559.

    Google Scholar 

  20. G. Chelnokov, N. Kharitonova, I. Bragin, and O. Chudaev, “Geochemistry of mineral water and gases of the Razdolnoe Spa (Primorye, Far East of Russia),” Appl. Geochem. 59, 147–154 (2015). doi 10.1016/japgeochem.2015.05.001

    Article  Google Scholar 

  21. H. J. W. De Baar, C. R. German, H. Elderfield, and P. van Gaans, “Rare earth element distributions in anoxic waters of the Cariaco Trench,” Geochim. Cosmochim Acta 52, 1203–1219 (1988). doi 10.1016/00167037(88)90275-X

    Article  Google Scholar 

  22. H. J. W. De Baar, J. Schijf, and R. H. Byrne, “Solution chemistry of the rare earth elements in seawater,” Eur. J. Solid State Inorg. Chem. 28, 357–373 (1991).

    Google Scholar 

  23. T. Duncan and T. J. Shaw, “The mobility of rare earth elements and redox sensitive elements in the groundwater/seawater mixing zone of a shallow coastal aquifer,” Aquat. Geochem. 9, 223–255 (2003). doi 10.1023/B:AQUA.0000022956.20338.26

    Article  Google Scholar 

  24. H. Elderfield, R. Upstill-Goddard, and E. R. Sholkovitz, “The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of ocean waters,” Geochim. Cosmochim. Acta 54, 971–991 (1990). doi 10.1016/0016-7037(90)90432-K

    Article  Google Scholar 

  25. Y. Erel and E. M. Stolper, “Modeling of rare-earth element partition between particles and solutions in aquatic environments,” Geochim. Cosmochim. Acta 57, 513–518 (1993).

    Article  Google Scholar 

  26. M. J. Gimeno, L. F. Auque, and D. K. Nordstrom, “REE speciation in low-temperature acidic waters and the competitive effect of aluminum,” Chem. Geol. 165, 167–180 (2000).

    Article  Google Scholar 

  27. D. C. Gosselin, M. R. Smith, E. A. Lepel, and J. C. Laul, “Rare earth elements in chloride-rich groundwater, Palo Duro Basin, Texas, USA,” Geochim. Cosmochim. Acta 56, 1495–1505 (1992). doi:10.1016/0016-7037(92)90219-9

    Article  Google Scholar 

  28. K. H. Johannesson, W. B. Lyons, M. A. Yelken, et al., “Geochemistry of rare earth elements in hypersaline and dilute acidic natural terrestrial waters: complexetion behavior and middle rare-earth element enrichments,” Chem. Geol. 133, 125–144 (1996).

    Article  Google Scholar 

  29. K. Johannesson, K. Stetchenbach, and V. Hodge, “Rare earth elements as geochemical tracers of regional groundwater mixing,” Geochim. Cosmochim. Acta 61, 3605–3618 (1997).

    Article  Google Scholar 

  30. K. H. Johannesson, I. M. Farnham, C. Guo, and K. J. Stetzenbach, “Rare earth element fractionation and concentration variations along a groundwater flow path within a shallow, basin-fill aquifer, southern Nevada, USA,” Geochim. Cosmochim. Acta 63, 2697–2708 (1999). doi 10.1016/S00167037(99)00184-2

    Article  Google Scholar 

  31. K. H. Johannesson and M. J. Hendry, “Rare earth element geochemistry of groundwaters from a thick till and clayrich aquitard sequence, Saskatchewan, Canada,” Geochim. Cosmochim. Acta 64, 1493–1509 (2000). doi 10.1016/S0016-7037(99)00402-0

    Article  Google Scholar 

  32. K. H. Johannesson, X. Zhou, C. Guo, K. J. Stetzenbach, and V. F. Hodge, “Origin of rare earth element signatures in groundwaters of circumneutral pH from southern Nevada and eastern California, USA,” Chem. Geol. 164, 239–257 (2000). doi 10.1016/S00092541(99)00152-7

    Article  Google Scholar 

  33. N. A. Kharitonova, G. A. Chelnokov, and E. A. Vakh, Rare earth elements geochemistry of sedimentary bedrock and groundwater from Lastochka Spa (northern part of Primorye, Russia),” in Proceedings of 12th International Symposium on the Water–Rock Interaction (WRI-12), Ed. by T. D. Bullen and Y. Wang (Taylor & Francis Group. London, 2007), pp. 969–972.

    Google Scholar 

  34. N. A. Kharitonova, G. A. Chelnokov, A. A. Karabtsov, and V. I. Kiselev, “Geochemistry of Na-HCO3 groundwater and sedimentary bedrocks from the central part of Sikhote-Aline Mountain Regison (Far East of Russia),” Appl. Geochem. 22, 1764–1776 (2007).

    Article  Google Scholar 

  35. N. A. Kharitonova, G. A. Chelnokov, E. A. Vakh, and N. V. Zarubina “Content and distribution of REEs in high pCO2 spas from Sikhote-Alin Ridge (Far East of Russia),” in Proceedings of the 13th International Symposium on the Water-Rock Interaction, Guanajuato, Mexico, 2010, Ed. by P. Birkler and I. S. Torres-Alvarado (Guanajuato, 2010), pp. 473–476.

    Google Scholar 

  36. M. G. Lawrence, A. Greig, K. D. Collerson, and B. S. Kamber, “Rare earth element and yttrium variability in South East Queensland waterways,” Aquat. Geochem. 12, 39–72 (2006). doi 10.1007/s10498-0054471-8

    Article  Google Scholar 

  37. P. Möller, G. Morteani, A. Fuganti, P. Dulski, and H. Gerstenberger, “Rare earth elements, yttrium and H, O, C, Sr, Nd, and Pb isotope studies in mineral waters and corresponding rocks from NW Bohemia, Czech Republic,” Appl. Geochem. 13, 975–994 (1998).

    Article  Google Scholar 

  38. P. Möller, P. Dulski, E. Salameh, and S. Geyer, “Characterization of the sources of thermal spring and well water in Jodan by rare earth elements and yttrium distribution and stable isotopes of H2O,” Acta Hydrochem. Hydrobiol. 34, 101–116 (2006).

    Article  Google Scholar 

  39. B. J. Nelson, S. A. Wood, and J. L. Osiensky, “Rare earth element geochemistry of groundwater in Palouse Basin, Northen Idaho–eastern Washington,” Geochem. Explor., Environ., Anal. 4, 227–241 (2004).

    Article  Google Scholar 

  40. D. L. Parkhurst and C. A. J. Appelo, “User’s guide to PHREEQC (Version 2)—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations,” U.S.Dept. Int., U.S.Geol. Surv., Techniques of Water-Resources Investigation, Report, 99–4259 (2000).

    Google Scholar 

  41. P. Shand and W. M. Edmunds, et al., High pCO2 cold springs of the Primorye region, Eastern Russia,” in 8th International Symposium on Water–Rock Interaction, (Vladivostok, 1995), pp. 393–396.

    Google Scholar 

  42. P. Shand, K. H. Johannesson, O. Chudaev, V. Chudaeva, W. M. Edmunds, “Rare earth contents of high pCO2 groundwaters of Primorye, Russia: mineral stability and complexation controls,” in Rare Earth Elements in Groundwater Flow System (Springer, 2005), pp. 161–186.

    Chapter  Google Scholar 

  43. E. R. Sholkovitz, “The aquatic chemistry of rare earth elements in rivers and estuaries,” Aquat. Geochem. 1, 1–34 (1995). doi 10.1007/BF01025229

    Article  Google Scholar 

  44. N. A. Tchepkaia, G. A. Chelnokov, A. A. Karabtsov, and I. A. Tarasenko, “Hydrochemical characteristics of Lastochka Spa (Primorye, Far East of Russia),” J. Geochem. Explor. 88, 148–152 (2006).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. A. Kharitonova.

Additional information

Original Russian Text © N.A. Kharitonova, E.A. Vakh, G.A. Chelnokov, O.V. Chudaev, I.A. Aleksandrov, I.V. Bragin, 2016, published in Tikhookeanskaya Geologiya, 2016, Vol. 35, No. 2, pp. 68–82.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kharitonova, N.A., Vakh, E.A., Chelnokov, G.A. et al. REE geochemistry in groundwater of the Sikhote Alin fold region (Russian Far East). Russ. J. of Pac. Geol. 10, 141–154 (2016). https://doi.org/10.1134/S1819714016020032

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1819714016020032

Keywords

Navigation