Abstract
The granitoids of the Dal’negorsk borosilicate deposit are ascribed mainly to the high-K metaluminous rocks of the calcic and alkali-calcic series. The thermo-baro-geo-chemical studies showed that they originated from melts with low contents of water (H2O < 3.5% H2O) and CO2 at 800–850°C and 65–90 MPa. The data on the average contents of elements in the rock-forming minerals and the estimated initial water content in the magma point to the absence of a genetic relation between the intrusion and boron mineralization. The granitoid magma was responsible for the skarn formation and for the mobilization and remobilization of boron under a favorable environment. The K/Ar dating (51.0 ± 10 Ma), the geochemical typification (signatures of within-plate, subduction, and collisional granitoids), and the low water content in the parental melts of the granitoids, in accordance with the scheme of the geodynamic evolution of the region, indicate their formation in the lithospheric plate sliding environment.
Similar content being viewed by others
References
V. A. Baskina, V. Yu. Prokof’ev, V. A. Lebedev, et al., “The Dal’negorsk borosilicate skarn deposit, Primorye, Russia: composition of ore-bearing solutions and boron sources,” Geol. Ore Dep. 51(3), 179–196 (2009).
V. A. Baskina, E. O. Dubinina, and A. S. Avdeenko, “On the nature of ore-bearing fluids on the Dal’negorskoe borosilicate deposit (Primor’e),” Dokl. Earth Sci. 436(1), 122–125 (2011).
G. A. Valui, “Petrological features of the granitoids of the East Sikhote Alin volcanic belt,” Tikhookean. Geol. 23(3), 37–51 (2004).
S. D. Velikoslavinskii, “Geochemical classification of silicic igneous rocks of major geodynamic environments,” Petrology 11(4), 327–342 (2003).
Geodynamics, Magmatism, and Metallogeny of East Russia, Ed. by A. I. Khanchuk (Dal’nauka, Vladivostok, 2006) [in Russian].
I. N. Govorov, “Minor alkaline intrusions and skarns of the Dal’negorsk district, Primorye,” Dokl. Akad. Nauk SSSR 230(1), 186–189 (1976).
V. V. Golozubov, Tectonics of the Jurassic and Lower Cretaceous Complexes of the Northwestern Pacific Margin (Dal’nauka, Vladivostok, 2006) [in Russian].
E. O. Dubinina, V. A. Baskina, and A. S. Avdeenko, “Nature of ore-forming fluids of the Dal’negorsk Deposit: isotopic and geochemical parameters of the altered host rocks,” Geol. Ore Dep. 53(1), 58–73 (2011).
N. P. Ermakov and Yu. A. Dolgov, Thermobarogeochemistry (Nedra, Moscow, 1979) [in Russian].
P. Leier and V. V. Ratkin, “The first direct 40Ar-39Ar-age determination for skarns of the Dal’negorsk ore region in the southern Far East, Russia,” Dokl. Earth Sci, 352(1), 15–17 (1997).
V. V. Lyakhovich, Trace Elements in the Rock-Forming Minerals of Granitoids (Nedra, Moscow, 1972) [in Russian].
S. V. Malinko, “Origin of endogenic boron deposits: data from typomorphic properties of the boron minerals,” Mineral. Zh. 7(1), 36–45 (1985).
S. V. Malinko and N. A. Nosenko, “Genetic relations of datolite of the Dal’negorsk deposit and problem of the genesis of borosilicate ores,” in Problems of Genetic and Applied Mineralogy (Nauka, Moscow, 1990), pp. 54–72 [in Russian].
S. V. Malinko, “Origin of unique accumulations of borosilicate ores of the Dal’negorsk deposit, Primorye,” Mineral. Zh. 14(5), 3–11 (1992).
S. V. Malinko, A. E. Lisitsyn, and Yu. P. Shergina, “Isotope-geochemical parameters of the formation of skarn-borosilicate mineralization in active continental margins,” Zap. Vseros. Mineral. O-va 123(4), 10–20 (1994).
M. V. Mints, V. N. Glaznev, A. N. Konilov, et al., Early Precambrian of the Northeastern Baltic Shield: Paleogeodynamics, Structure, and Evolution of the Continental Crust (Nauch. mir, Moscow, 1996) [in Russian].
L. F. Mishin, “Eu geochemistry in magmatic rocks of continental marginal volcanic belts,” Geochem. Int. 48(6), 580–592 (2010).
V. B. Naumov, “Determination of concentration and pressure of volatiles in magmatic melts,” Geokhimiya, No. 7, 997–1007 (1979).
N. A. Nosenko, Extended Abstract of Candidate’s Dissertation in Geology and Mineralogy (Vladivostok, 1986).
N. A. Nosenko, V. V. Ratkin, P. I. Logvenchev, et al., “Dal’negorsk borosilicate deposit as a product of polychronous skarnification,” Dokl. Akad. Nauk SSSR 312(1), 178–182 (1990).
N. A. Nosenko, “Geological structure and conditions of the formation of the Dal’negorskboron deposit: estimation of reserves of the datolite and woolastonite ores of deep horizons at 01.01.1996,” Report of Geological Prospecting Team of OAO “Bor” based on the results of searching for boron ores at the deep horizons of the Dal’negorsk boron deposit in 1974–1989 (Dal’negorsk, 1996).
V. V. Ratkin, L. N. Khetchikov, N. V. Gnidash, et al., “Role of colloids and paleohydrothermal cavities in the formation of rhythmically banded ores of the Dal’negorsk borosilicate deposit,” Dokl. Ross. Akad. Nauk 325(6), 1214–1217 (1992).
V. V. Ratkin and B. N. Watson, “Dal’negorsk skarn borosilicate deposit, southern Russian Far East: geology and boron source based on isotope data,” Tikhookean. Geol., No. 6, 95–102 (1993).
V. V. Ratkin, I. N. Tomson, M. D. Ryazantseva, et al., “Correlation between the ore isotope geochemical and petrophysical zonations of the eastern Sikhote Alin volcano-plutonic belt,” Dokl. Earth Sci. 356(3), 990–993 (1997).
E. Roedder, Fluid Inclusions in Minerals, Mineral. Soc. Am., Rev. Mineral. 12 (1984).
E. Roedder, Fluid Inclusions in Minerals, Mineral. Soc. Am., Rev. Mineral. 12 (1984).
F. G. Reif, Physicochemical Conditions of the Formation of Large Granitoid Massifs of the Eastern Baikal Region (Nauka, Novosibirsk, 1976) [in Russian].
F. G. Reif, Ore-Forming Potential of the Granites and Conditions of its Manifestation (Nauka, Moscow, 1990) [in Russian].
L. V. Tauson, “Granitoid magmas as source of ore matter of endogenous deposits,” in Ore Sources of Endogenous Deposits (Nauka, Moscow, 1976), pp. 43–57 [in Russian].
A. I. Khanchuk, V. V. Golozubov, Yu. A. Martynov, et al., “Early Cretaceous and Paleogene Californian-type transform continental margins, Russian Far East,” in Tectonics of Asia (GEOS, Moscow, 1997), pp. 240–243 [in Russian].
A. I. Khanchuk, “Paleogeodynamic analysis of the formation of ore deposits of the Russian Far East,” in Ore Deposits of the Continental Margins (Dal’nauka, Vladivostok, 2000), pp. 5–34 [in Russian].
A. I. Khanchuk, Yu. A. Martynov, A. B. Perepelov, et al., “Magmatism of the zones of transform plate boundaries: new data and prospects,” in Volcanism and Geodynamics (Inst. Volcanol. Seismol. Dal’nevost. Otd. Ross. Akad. Nauk, Petropavlovsk-Kamchatskii, 2009), Vol. 1, pp. 32–37 [in Russian].
A. I. Khanchuk, “Geodynamics, magmatism, and metallogeny of the continent-ocean transition zones,” in New Horizons in Study of Magma and Ore Formation (Moscow, 2010), pp. 169–170 [in Russian].
L. N. Khetchikov, V. A. Pakhomova, V. I. Gvozdev, et al., “Peculiarities of fluid regime of some granitoid systems of Primorye,” Preprint (Dal’nevost. Geol. Inst. Dal’nevost. Otd. Akad. Nauk SSSR, Vladivostok, 1991).
V. P. Chupin and O. N. Kosukhin, “Diagnostics and technique of study of melt inclusions in the minerals of granitoids and pegmatites,” Geol. Geofiz., No. 10, 66–73 (1982).
E. L. Shkol’nik, V. I. Gvozdev, S. V. Malinko, et al., “Nature of the borosilicate mineralization of the Dal’negorsk deposit, Primorye,” Tikhookean. Geol. 22(3), 122–134 (2003).
Yu. P. Yushmanov and A. M. Petrishchevskii, Tectonics, Deep Structure, and Metallogeny of the Coastal Zone of the Southern Sikhote-Alin (Dal’nauka, Vladivostok, 2004) [in Russian].
N. B. Harris, J. A. Pearce, and A. G. Tindle, “Geochemical characteristics of collision-zone magmatism,” in Collision Tectonics, Ed. by M. P. Coward and A. C. Ries, Geol. Soc. Spec. Publ. 19, 67–81 (1986).
S. S. Sun and W. F. McDonough, “Chemical and isotopic systematics of oceanic basalts: implication for mantle composition and processes,” in Magmatism in the Oceanic Basins, Ed. by A. D. Saunders and M. S. Norry (Blackwell, Oxford, 1989), pp. 313–345.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.A. Karas’, V.A. Pakhomova, N.I. Ekimova, 2014, published in Tikhookeanskaya Geologiya, 2014, Vol. 33, No. 3, pp. 67–78.
Rights and permissions
About this article
Cite this article
Karas’, O.A., Pakhomova, V.A. & Ekimova, N.I. Granitoid massif of the Dal’negorsk borosilicate deposit in the Primorye region of Russia: The role of the intrusion in the formation of the boron mineralization. Russ. J. of Pac. Geol. 8, 213–223 (2014). https://doi.org/10.1134/S181971401403004X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S181971401403004X