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General trends in concentration and temperature behavior of equivalent conductance of N,N-diallylammonium polymers aqueous solutions: Effect of counterion nature and amine structure

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Abstract

The specific and equivalent conductivity of the diluted aqueous solutions of diallyammonium polyelectrolytes, initial monomers (N,N-diallylammonium trifluoroacetate, N,N-diallyl-N-methylammonium trifluoroacetate, N,N-diallyl-N,N-dimethylammonium chloride), and also potassium trifluoroacetate and trifluoroacetic acid solutions are studied. The limiting ionic mobility of diallylammonium cations and trifluoroacetate anion are found. The regularities of concentration changes in the equivalent conductance of polyelectolytes solutions are established. The degree of dissociation of diallyammonium polymers is shown to depend both on the counterion nature and on the amine structure.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    L. M. Timofeeva, A. S. Lileev & Yu. A. Simonova

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    I. V. Balakaeva & A. K. Lyashchenko

Authors
  1. L. M. Timofeeva
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  2. I. V. Balakaeva
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  3. A. S. Lileev
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  4. Yu. A. Simonova
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  5. A. K. Lyashchenko
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Correspondence to L. M. Timofeeva.

Additional information

Original Russian Text © L.M. Timofeeva, I.V. Balakaeva, A.S. Lileev, Yu.A. Simonova, A.K. Lyashchenko, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya C, 2017, Vol. 59, No. 1, pp. 149–156.

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Timofeeva, L.M., Balakaeva, I.V., Lileev, A.S. et al. General trends in concentration and temperature behavior of equivalent conductance of N,N-diallylammonium polymers aqueous solutions: Effect of counterion nature and amine structure. Polym. Sci. Ser. C 59, 141–148 (2017). https://doi.org/10.1134/S1811238217010131

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  • DOI: https://doi.org/10.1134/S1811238217010131

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