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Highly phenylated polyarylenes: Synthesis, properties, and applications

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Abstract

The syntheses of highly phenylated polyarylenes (polyphenylenes, polyalkylenephenylenes, poly(phenylene oxides), poly(phenylene sulfides), poly(phenylene ketones), and poly(phenylene ethynylenes)) based on the interaction of hexaphenyl-substituted bis(cyclopentadienes) of the appropriate structure with diethynylarylenes via the Dields-Alder reaction are considered. Polymers containing no less than six phenyl substituents per repeating unit and characterized by the isomerism of backbone chains combine unique solubility in common organic solvents with excellent thermal characteristics. Highly phenylated polyarylenes are of interest as materials for electronics, microelectronics, membrane techniques, and fuel cells.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    A. L. Rusanov & N. M. Belomoina

  2. Materials Research Institute, National Autonomous University of Mexico, University City, Mexico, D.F., 04510, Mexico

    D. Yu. Likhachev

  3. United Research and Development Centre, Leninskii pr. 55/1, str. 2, Moscow, 119333, Russia

    P. V. Kostoglodov

Authors
  1. A. L. Rusanov
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  2. D. Yu. Likhachev
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  3. P. V. Kostoglodov
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  4. N. M. Belomoina
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Correspondence to A. L. Rusanov.

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Original Russian Text © A.L. Rusanov, D.Yu. Likhachev, P.V. Kostoglodov, N.M. Belomoina, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. C, 2008, Vol. 50, No. 7, pp. 1344–1369.

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Rusanov, A.L., Likhachev, D.Y., Kostoglodov, P.V. et al. Highly phenylated polyarylenes: Synthesis, properties, and applications. Polym. Sci. Ser. C 50, 39–62 (2008). https://doi.org/10.1134/S1811238208010037

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