Skip to main content
SpringerLink
Log in

Grafting Polybutadiene onto Surfaces of Talcum Powder by Spray-Drying Technology and Modification of EPDM Rubber

  • COMPOSITES
  • Published:
Polymer Science, Series B Aims and scope Submit manuscript

Abstract

In this contribution, we reported the investigation of EPDM rubber reinforced by talcum grafted polybutadiene (MSi-Talc). First, poly (3-methacryloxypropyltrimethoxysilane)-b-polybutadiene-b-poly(3-methacryloxypropyltrimethoxysilane) (PMSi-b-PB-b-PMSi) triblock copolymer was synthesized by esterification reaction and RAFT polymerization of 3-methacryloxypropyltrimethoxysilane. Second, talcum powder (Talc) was spraying with PMSi-b-PB-b-PMSi solution and drying to obtain modified talc (MSi-Talc). MSi-Talc and Talc were incorporated into EPDM simultaneously. It was found that Talc in the EPDM/MSi-Talc vulcanizates was much better distributed and dispersed than in the EPDM/Talc composites. Compared to Talc dispersion and Talc-rubber interaction of the EPDM/Talc composites, the mechanical properties (tensile strength, elongation at break, and tear strength) of the EPDM/MSi-Talc composites were significantly improved, and the compression set of the EPDM/MSi-Talc composites was greatly decreased and much lower than that of the EPDM/Talc composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.
Fig. 11.
Fig. 12.
Fig. 13.

REFERENCES

  1. S. Wolff, M. Wang, and E. Tan, Rubber Chem. Technol. 66, 163 (1993).

    Article  CAS  Google Scholar 

  2. E. M. Dannenberg, Rubber Chem. Technol. 48, 410 (1975).

    Article  CAS  Google Scholar 

  3. C. Dai and T. Huang, Appl. Clay Sci. 15, 51 (1999).

    Article  CAS  Google Scholar 

  4. H. Kursun and U. Ulusoy, Int. J. Miner. Process. 78, 262 (2005).

    Article  Google Scholar 

  5. G. I. Ryzhikova, A. N. Bauman, M. A. Volkov, Y. M. Kazakov, S. I. Volfson, N. A. Okhotina and O. A. Panfilova, Russ. J. Appl. Chem. 88, 1679 (2015).

    Article  CAS  Google Scholar 

  6. A. Buzarovska, G. Bogoeva-Gaceva, and R. Fajgar, J. Polym. Eng. 36, 181 (2016).

    Article  CAS  Google Scholar 

  7. S.C. Jana and S. Jain, Polymer 42, 6897 (2001).

    Article  CAS  Google Scholar 

  8. Y. Lin, A. Zhang, J. Sun, and L. Wang, J. Macromol. Sci., Part B: Phys. 52, 1494 (2013).

    Article  Google Scholar 

  9. M. R. Turner, E. Duguet, and C. Labrugere, Surf. Interface Anal. 25, 917–923 (1997).

    Article  CAS  Google Scholar 

  10. J. Ramier, C. Gauthier, L. Chazeau, L. Stelandre, and L. Guy, J. Polym. Sci. B: Polym. Phys. 45, 286 (2007).

    Article  CAS  Google Scholar 

  11. S. H. Sheikh, X. Yin, A. Ansarifar, and K. Yendall, J. Reinf. Plast. Comp. 36, 1132 (2017).

    Article  CAS  Google Scholar 

  12. M. Rong, M. Zhang, Y. Zheng, H. Zeng, R. Walter, and K. Friedrich, Polymer 42, 167 (2001).

    Article  CAS  Google Scholar 

  13. D. N. Bikiaris, G. Z. Papageorgiou, E. Pavlidou, N. Vouroutzis, P. Palatzoglou, and G. P. Karayannidis, J. Appl. Polym. Sci. 100, 2684 (2006).

    Article  CAS  Google Scholar 

  14. Y. Yu, M. Rong, and M. Zhang, Polymer 51, 492 (2010).

    Article  CAS  Google Scholar 

  15. Y. Zhang, A. Zhang, L. Kang, Y. Zhang, Polym. Sci., Ser. A 62, 407 (2020).

    Article  Google Scholar 

  16. B. Zhao and L. Zhu, J. Am. Chem. Soc. 128, 4574 (2006).

    Article  CAS  PubMed  Google Scholar 

  17. C. Liu and C. Pan, Polymer 48, 3679 (2007).

    Article  CAS  Google Scholar 

  18. T. Morinaga, M. Ohkura, K. Ohno, Y. Tsujii, and T. Fukuda, Macromolecules 40, 1159 (2007).

    Article  CAS  Google Scholar 

  19. T. Wu, Y. Zhang, X. Wang, and S. Liu, Chem. Mater. 20, 101 (2008).

    Article  CAS  Google Scholar 

  20. G. Zong, H. Chen, R. Qu, C. Wang, and N. Ji, J. Hazard. Mater. 186, 614 (2011).

    Article  CAS  PubMed  Google Scholar 

  21. S. Perrier, P. Takolpuckdee, and C. A. Mars, Macromolecules 38, 6770 (2005).

    Article  CAS  Google Scholar 

  22. Y. Zhao and S. Perrier, Macromolecules 40, 9116 (2007).

    Article  CAS  Google Scholar 

  23. A. Rungta, B. Natarajan, T. Neely, D. Dukes, L. S. Schadler, and B. C. Benicewicz, Macromolecules 45, 9303 (2012).

    Article  CAS  Google Scholar 

  24. P. S. Chinthamanipeta, S. Kobukata, H. Nakata, and D. A. Shipp, Polymer 49, 5636 (2008).

    Article  CAS  Google Scholar 

  25. M. M. Khani, Z. M. Abbas, and B. C. Benicewicz, J. Polym. Sci., Part A: Polym. Chem. 55, 1493 (2017).

    Article  CAS  Google Scholar 

  26. D. Tumnantong, G. L. Rempel, and P. Prasassarakich, Polym. Eng. Sci. 58, 759 (2018).

    Article  CAS  Google Scholar 

  27. A. Kongsinlark, G. L. Rempel, and P. Prasassarakich, Chem. Eng. J. 193, 215 (2012).

    Article  Google Scholar 

  28. D. Tumnantong, G. L. Rempel, and P. Prasassarakich, Polymers 9, 637 (2017)

    Article  PubMed  PubMed Central  Google Scholar 

  29. Y. Xiang, X. Shen, J. Gao, A. M. Asiri, and H. M. Marwani, Polym. Eng. Sci. 59, 1167 (2019).

    Article  CAS  Google Scholar 

  30. Y. Hua, H. Zhao, Y. Xiang, X.Shen, Y. Fang, and J. Gao, Polym. Eng. Sci. 62, 939 (2022).

    Article  CAS  Google Scholar 

  31. Y. Geng, H. Zhao, Y. Xiang, H. Cong, X. Shen, and J. Gao, Colloid Polym. Sci. 300, 927 (2022).

    Article  CAS  Google Scholar 

  32. J. T. Lai, D. Filla, and R. Shea, Macromolecules 35, 6754 (2002).

    Article  CAS  Google Scholar 

  33. S.S . Sarkawi, W. K. Dierkes, and J. W. Noordermeer, Eur. Polym. J. 54, 118 (2014).

    Article  CAS  Google Scholar 

  34. A. Sepehri, M. Razzaghi-Kashani, and M. H. R. Ghoreishy, J. Appl. Polym. Sci. 125, E204 (2012).

Download references

Funding

This work was financially supported the Key Research and Development Project of Anhui Province (2022a05020009), Science and Technology Plan Project of Huangshan City (2021KC-05), the Engineering Research Project of Anhui Polytechnic University (HX-2021-09-007).

Author information

Authors and Affiliations

  1. Anhui Laboratory of Clean Catalytic Engineering, and School of Chemical and Environmental Engineering, Anhui Polytechnic University, 241000, Wuhu, China

    Yuxing Wang, Qilai Wang, Suyuan Zhao, Xianrong Shen & Yixin Xiang

  2. College of Materials Engineering, Xuzhou College of Industrial Technology, 221140, Xuzhou, China

    Houluo Cong

  3. Huangshan Shangyi Rubber and Plastic Products Co., Ltd, 245200, Huangshan, China

    Yijun Chen

Authors
  1. Yuxing Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qilai Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Suyuan Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Houluo Cong
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yijun Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Xianrong Shen
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yixin Xiang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Houluo Cong or Yixin Xiang.

Ethics declarations

The authors of this work declare that they have no conflicts of interest.

Additional information

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yuxing Wang, Wang, Q., Zhao, S. et al. Grafting Polybutadiene onto Surfaces of Talcum Powder by Spray-Drying Technology and Modification of EPDM Rubber. Polym. Sci. Ser. B 65, 980–990 (2023). https://doi.org/10.1134/S1560090424600116

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090424600116

Search

Navigation