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Periodic Donor-Acceptor (Co)polyarylenephthalides with Tunable Photoluminescent Parameters

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Abstract

The macromonomers of the dyad (OYO) and triad (OYOYO, OYTYO) structure (with О being diphenylene oxide, T being terphenylene, and Y being the phthalide cycle) as well as a series of (co)poly-arylenephthalides with general formula [(OY)p(TY)q]n differing in the ratio between the diphenyleneoxyphthalide p and terphenylenephthalide q groups (p : q = 0 : 1, 1 : 1, 2 : 1, 3 : 1, 1 : 0) have been synthesized. Photooptical and emission properties of the solutions and thin films of the synthesized (co)polymers and their aggregates formed upon the addition of a bad solvent have been investigated.

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ACKNOWLEDGMENTS

The luminescence and NMR spectra were recorded using the equipment of the Centers for Collective Usage “Chemistry” and “Agidel”, Ufa Institute of Chemistry, Ufa Federal Research Center, RAS.

This study was performed in the scope of the State Task (topics nos. 122031400279-9, 122031400282-9, 122031400255-3, and 075-00697-22-00) from Ministry of Science and Higher Education of the Russian Federation.

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Authors and Affiliations

  1. Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences, 450054, Ufa, Russia

    V. A. Kraikin, A. A. Fatykhov, N. G. Gileva, T. A. Yangirov, S. S. Ostakhov, R. R. Kayumova & A. V. Mamykin

  2. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    S. N. Salazkin

Authors
  1. V. A. Kraikin
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  2. A. A. Fatykhov
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  3. N. G. Gileva
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  4. T. A. Yangirov
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  5. S. S. Ostakhov
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  6. R. R. Kayumova
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  7. A. V. Mamykin
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  8. S. N. Salazkin
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Correspondence to V. A. Kraikin.

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Translated by E. Karpushkin

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Kraikin, V.A., Fatykhov, A.A., Gileva, N.G. et al. Periodic Donor-Acceptor (Co)polyarylenephthalides with Tunable Photoluminescent Parameters. Polym. Sci. Ser. B 65, 58–68 (2023). https://doi.org/10.1134/S1560090423700719

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  • DOI: https://doi.org/10.1134/S1560090423700719

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