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Synthesis, Characterization, and Microbial Degradation Behavior of Hydrogel Based on Poly(ε-caprolactone) and Methacrylic Anhydride

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Abstract

This study establishes the synthesis of a biodegradable hydrogel based on poly(ε-caprolactone) and methacrylic anhydride. The process was performed by polymerizing ε-caprolactone with methacrylic anhydride and catalyzed by the protonated heterogeneous clay maghnite-H+, followed by the thermal-radical polymerization of the resulting α,ω-bis-unsaturated PCL macromonomers. The structure and functionalization of the obtained macromonomers were confirmed by Fourier transform infrared spectroscopy, proton and carbon nuclear magnetic resonance, and UV-spectroscopy. In addition, the kinetic study of the effect of different experimental parameters (amounts of maghnite-H+, temperature, reaction time, and methacrylic anhydride content) on the polymerization process has been discussed. The swelling behavior and thermal properties of hydrogel were investigated in detail as well as the biodegradability efficiency of the produced hydrogel against the gram-positive (Bacillus subtilis) bacteria.

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Authors and Affiliations

  1. Laboratory of Organic Chemistry Macromolecular and Materials, Faculty of Exact Sciences, University of Mascara, 29000, Mascara, Algeria

    Fatima El Zohra Aris, Aicha Hachemaouia & Ahmed Yahiaoui

  2. Engineering Physics Laboratory, University of Tiaret, 14000, Tiaret, Algeria

    Abdelkader Dehbi

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  1. Fatima El Zohra Aris
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Fatima El Zohra Aris, Hachemaouia, A., Yahiaoui, A. et al. Synthesis, Characterization, and Microbial Degradation Behavior of Hydrogel Based on Poly(ε-caprolactone) and Methacrylic Anhydride. Polym. Sci. Ser. B 64, 417–428 (2022). https://doi.org/10.1134/S156009042270018X

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